Browsing by Author "Zhou, Xiaobing"
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Item Bulk electric conductivity response to soil and rock CO2 concentration during controlled CO2 release experiments: Observations & analytic modeling(2015-09) Jewell, Scott; Zhou, Xiaobing; Apple, Martha E.; Dobeck, Laura M.; Spangler, Lee H.; Cunningham, Alfred B.To develop monitoring technologies for geologic CO2 storage, controlled CO2 release experiments at the Zero Emissions Research and Technology (ZERT) site in Bozeman, Montana, USA, were carried out in 2009-2011. To understand the impact on the electric properties of soil and sediment rock due to possible CO2 leakage, we have developed an analytical model to explain and predict the electric conductivity (EC) for CO2 impacted soil and sedimentary rock. Results from the model were compared with the measurements at the ZERT site during 2009–2011 and the CO2-Vadose Project site in France in 2011-2012 after model calibration at each site. The model was calibrated using the saturation (n) and cementation (m) exponents contained in Archie's equation, and a chemistry coefficient (pKc) as tuning parameters that minimized the misfit between observed and modeled soil/rock bulk conductivity data. The calibration resulted in n=3.15, m=2.95, and pKc=4.7 for the ZERT site, which was within the range of values in the literature. All the ZERT data sets had rms errors of 0.0115-0.0724. For the CO2-Vadose site, calibration resulted in n=3.6-9.85 and m=2.5-4.2, pKc=4.80-5.65, and the rms error of 0.0002-0.0003; the cementation exponents were consistent with the literature. These results found that the model predicted the bulk EC reasonably well in soil and rock once the unmeasurable model parameters (n, m, and pKc) were calibrated.Item Experimental observation of signature changes in bulk soil electrical conductivity in response to engineered surface CO2 leakage(2012-03) Zhou, Xiaobing; Lakkaraju, V. R.; Apple, Martha E.; Dobeck, Laura M.; Gullickson, K.; Shaw, Joseph A.; Cunningham, Alfred B.; Wielopolski, Lucian; Spangler, Lee H.Experimental observations of signature changes of bulk soil electrical conductivity (EC) due to CO2 leakage were carried out at a field site at Bozeman, Montana, to investigate the change of soil geophysical properties in response to possible leakage of geologically sequestered CO2. The dynamic evolution of bulk soil EC was measured during an engineered surface leakage of CO2 through in situ continuous monitoring of bulk soil EC, soil moisture, soil temperature, rainfall rate, and soil CO2 concentration to investigate the response of soil bulk EC signature to CO2 leakage. Observations show that: (1) high soil CO2 concentration due to CO2 leakage enhances the dependence of bulk soil EC on soil moisture. The bulk soil EC is a linear multivariate function of soil moisture and soil temperature, the coefficient for soil moisture increased from 2.111 dS for the non-leaking phase to 4.589 dS for the CO2 leaking phase; and the coefficient for temperature increased from 0.003 dS/°C for the non-leaking phase to 0.008 dS/°C for the CO2 leaking phase. The dependence of bulk soil EC on soil temperature is generally weak, but leaked CO2 enhances the dependence,(2)after the CO2 release, the relationship between soil bulk EC and soil CO2 concentration observes three distinct CO2 decay modes. Rainfall events result in sudden changes of soil moisture and are believed to be the driving forcing for these decay modes, and (3) within each mode, increasing soil CO2 concentration results in higher bulk soil EC. Comparing the first 2 decay modes, it is found that the dependence of soil EC on soil CO2 concentration is weaker for the first decay mode than the second decay mode.