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Item Modeling saline fluid flow in subglacial ice-walled channels(Montana State University - Bozeman, College of Letters & Science, 2022) Jenson, Amy Jo; Chairperson, Graduate Committee: Scott McCallaSubglacial hydrological systems have impacts on ice dynamics as well as nutrient and sediment transport. There has been an extensive effort to understand the dynamics of subglacial drainage through numerical modeling, however these models have focused on freshwater, neglecting the consideration of brine. Saline fluid can exist in cold-based glacier systems where freshwater cannot. Therefore, there exist subglacial hydrological systems where the only fluid is brine. Understanding the routing of saline fluid is important for understanding geochemical and microbiological processes in these saline cryospheric habitats. In this thesis, I present a model of channelized drainage from a hypersaline subglacial lake and highlight the impact of saline fluid on melt rates in an ice-walled channel. The model results show that channel walls grow more quickly when fluid contains higher salt concentrations, which results in greater peak discharge and faster drainage for a fixed lake volume. This model provides a framework to assess the relative impact of brine on discharge and drainage duration.Item Influence of lithogenic energy on subglacial microbial community composition(Montana State University - Bozeman, College of Agriculture, 2021) Dunham, Eric Corwin; Chairperson, Graduate Committee: Eric Boyd; John E. Dore, Mark L. Skidmore, Eric E. Roden and Eric S. Boyd were co-authors of the article, 'Lithogenic hydrogen supports microbial primary production in subglacial and proglacial environments' in the journal 'Proceedings of the National Academy of Sciences of the United States of America' which is contained within this dissertation.; K. Rebecca Mitchell, Mark L. Skidmore and Eric S. Boyd were co-authors of the article, 'Influence of ferric iron on community composition in a basaltic glacial catchment' which is contained within this dissertation.Chemosynthesis, the generation of biomass using chemical energy, supported life on early Earth and continues to sustain contemporary light-independent ecosystems. The mechanisms of nutrient release from the geosphere are critical to understanding the present and historical distribution and diversity of life. Glaciers release such nutrients through comminution of bedrock, continuously resurfacing reactive minerals that can be colonized and exploited by chemosynthetic microorganisms. Bedrock mineralogy influences the nutrients available in these environments, but little is known about which nutrients are most important or how they affect microbial community composition, particularly in catchments overlying igneous bedrock like basalt. Iron and silicate minerals, common in basalt, readily generate both reductants such as H 2 and oxidants such as Fe(III) through interactions with water. Abundant H 2 in meltwaters of the basalt-based Icelandic glacier Kotlujokull (KJ) were found to support sediment microbial communities better adapted to use H 2 in chemosynthetic metabolism than those found beneath the carbonate-based Robertson Glacier (RG), Canada. KJ communities exhibited shorter lag-times and faster rates of net H 2 oxidation and dark carbon dioxide (CO 2) fixation than those from RG. A KJ sediment enrichment culture provided with H 2, CO 2, and Fe(III) produced a chemolithoautotrophic population related to Rhodoferax ferrireducens, which was also detected using molecular techniques in sediments from Kaldalonsjokull (Kal), another basalt-based Icelandic glacier. The abundance and composition of microbial communities that colonized defined minerals incubated for 12 months in Kal meltwater streams were examined by extracting DNA and sequencing PCR-amplifiable 16S rRNA genes. DNA quantities and the composition of 16S rRNA genes recovered from Kal sediments were most similar to those recovered from incubated Fe(III)-bearing minerals hematite and magnetite, with putative Fe(III) reducers dominating all three communities. These findings point to the importance of bedrock mineral composition in influencing the supplies of nutrients like H 2 and Fe(III) that, in turn, influence the diversity, abundance, and activity of microbial communities in subglacial environments. They further indicate the potential for subglacial habitats to serve as refugia for microbial communities in the absence of sunlight, such as during Snowball Earth episodes, or on icy planets without photosynthetic life.Item Hydrogen production from mechanically-activated basalt under experimental conditions simulating subglacial environments(Montana State University - Bozeman, College of Letters & Science, 2019) Mitchell, Kari Rebecca; Chairperson, Graduate Committee: Mark L. SkidmoreShearing of rocks containing silicate followed by reaction with water has previously been shown to produce hydrogen under experimental conditions relevant to subglacial environments. The abiotic production of hydrogen, carbon dioxide, methane, and other hydrocarbon gases has also been demonstrated in laboratory comminution experiments on rocks from glaciated catchments. Thus, the generation of these biologically useful gases (e.g. hydrogen and methane) beneath glaciers could serve as a source of reductant capable of sustaining microbial ecosystems beneath the ice. Despite the ubiquitous nature of basalt on both Earth and other planetary bodies, production of hydrogen and other gases from basalt through mechanical shearing and reaction with water has not been demonstrated. Basalts were collected from glaciated catchments in Iceland to test whether hydrogen and other gases were produced under laboratory conditions simulating glacial comminution. Rock samples were milled under an inert atmosphere, after which water was added and hydrogen and methane production measured over time. An average of 6.6 nmol hydrogen and 2.6 nmol methane per gram rock were produced after 168 hours from basalt samples tested; additionally, hydrogen peroxide and radicals were produced during grinding. The abiogenic production of hydrogen and methane under these simulated subglacial basaltic environments demonstrated in this study also has implications for supporting subglacial microbial communities during periods of extended glaciation, such as glacial-interglacial cycles in the Pleistocene and during the pervasive low-latitude glaciation of the Cryogenian. This mechanism of hydrogen production also has implications for the potential for life on icy worlds like Mars.Item Geochemical characterization of shallow sediments from the grounding zone of the Whillans Ice Stream(Montana State University - Bozeman, College of Agriculture, 2019) Roush, Kimberly Anne; Chairperson, Graduate Committee: John C. Priscu and John Dore (co-chair); John Priscu, Mark Skidmore, Alex Michaud and the WISSARD Science Team were co-authors of the article, 'Signatures of subglacial water in shallow sediments of the Whillans grounding zone and overlying water column' which is contained within this thesis.; John Priscu, John Dore, Wei Li, Tristy Vick-Majors and the WISSARD Science Team were co-authors of the article, 'Sediment porewater organic matter content' which is contained within this thesis.The research presented in this thesis focused on subglacial flow beneath the West Antarctic Ice Sheet (WAIS) and its potential influence near the grounding zone. Antarctic grounding zones are of specific scientific interest because they can impact the stability of the continental ice sheet and its breakup, potentially resulting in significant sea level rise. My major objective was to determine whether there was influence of subglacial water at the Whillans Grounding Zone (WGZ) on the Siple Coast of the WAIS. A gravity corer was used to collect a 70 cm sediment core through 780 m of ice borehole drilled using a hot water clean access drilling system. The core was collected in a marine embayment adjacent to the WGZ beneath a 10 m water column. I used a combination of geochemical, isotopic and organic matter analyses to characterize the benthic sediments, porewater and water column. The geochemical and isotopic data showed the influence of subglacial freshwater on sediment porewater at specific depths in the 70 cm core. Vertical gradients of chloride and sulfate between surficial sediment and the overlying water column indicated ion diffusion from porewater to the column water. Dissolved organic matter concentration of sediment porewater and the overlying water column also indicated upward diffusion occurs from porewater to the overlying seawater. Sediment particulate carbon and nitrogen data showed that benthic sediments were more depleted in nitrogen than the overlying seawater. Sediment particulate carbon and nitrogen data showed that benthic sediments were more depleted in nitrogen than the overlying seawater. Geochemical, isotopic and organic matter data supports the influence of subglacial freshwater at the WGZ.Item Glacial effects on stream water nitrate: an examination of paired catchments in southern Montana(Montana State University - Bozeman, College of Letters & Science, 2019) Allen, Jordan Jon; Chairperson, Graduate Committee: Mark L. Skidmore and Jean Dixon (co-chair)Nitrogen is frequently a limiting nutrient in biologic systems. Previous research on alpine streams and lakes in the Beartooth Mountains, Montana/Wyoming has demonstrated nitrate concentrations in waters draining glaciated catchments that are up to ten times greater than comparable adjacent non-glaciated catchments. The enhanced nitrate concentrations in the glacial fed lakes have been associated with increased diatom abundance relative to the snow fed-lakes. However, the source of the enhanced nitrate input remained undetermined, as well as how nitrate concentrations vary temporally during summer melt. This study measured concentrations of nitrate and ammonium and the isotopic composition of nitrate over the 2016 melt-season in a paired catchment system, in the Beartooth Mountains, Montana. The two catchments have similar elevations, atmospheric inputs, bedrock geology, area, and contain lakes, however, one catchment contains a glacier, the other does not. The stream waters in the glaciated catchment showed significantly elevated nitrate concentrations relative to those in the non-glaciated catchment and to catchment atmospheric input, as determined by snowpack nitrate concentrations. Nitrate concentrations in the glacial stream were observed to increase both temporally as the melt-season progressed, and spatially, with distance downstream from the glacier terminus. Ammonium concentrations in the glacial stream were highest close to the glacier terminus, declining with distance downstream, but also increasing during the melt season. Nitrate isotopic values distinguish the stream waters from atmospheric inputs indicating additional nitrate sources in the catchment. Potential additional sources include inorganic nitrogen released from bedrock sources and microbially fixed nitrogen. Abiotic laboratory weathering experiments simulating subglacial conditions reacted deionized water with finely milled bedrock at 4°C, and a modest quantity of ammonium was released. Potassium is often replaced by ammonium in minerals. Rocks from the study area contained ~3% potassium by weight. Ammonium could then be converted to nitrate through microbial processes within the proglacial environment adding to the atmospheric nitrate input to the stream nitrate budget. However, estimated rates of sediment production, and by inference ammonium production, cannot account for the observed nitrate concentrations and flux, indicating an additional nitrate source, which is most likely ultimately derived from microbial nitrogen fixation.Item Landslide morphology and its insight into the timing and causes of slope failure: case study of post-glacial landslides in Yellowstone National Park(Montana State University - Bozeman, College of Letters & Science, 2018) Nicholas, Grace Ellen; Chairperson, Graduate Committee: Jean DixonLandslides are ubiquitous to post-glacial landscapes worldwide. Withdrawal of glacier ice exposes over-steepened landscapes that may be unstable, and consequently susceptible to landsliding. Glacial debuttressing may directly destabilize slopes; however, seismicity and transitions to interglacial climates associated with greater effective moisture and subsequent degradation of permafrost may also play a role. Here, we explore disparate potential mechanisms of slope failure in a set of post-glacial landslides in northwest Yellowstone National Park. We quantify spatial relationships, topographic metrics, and relative age of eight landslides within the north entrance to the park, a system traversed by over 700,000 visitors every year. Analysis of high-resolution topography indicates increasing surface roughness of non-active landslides southward. These roughness values in ancient slides are roughly half those of the active Slide Lake Landslide, and suggest younging ages along the retreat path of the Yellowstone Ice Cap, consistent with glacial debutressing as the likely trigger for these slides. However, roughness values and their application for relative age dating are strongly confounded by topographic biases such as gullying, fluvial erosional contacts, and anthropogenic features (e.g., roads, structures). Once roughness biases are removed, we find roughness differences between landslides decrease, and do not support younging ages along the path of ice retreat. Thus, glacial debuttressing most likely only had a preparatory influence on slope failure, and was not the direct trigger. Analysis of subsurface soils at landslide toes indicate a >17 plasticity index, pointing to highly expansive clays that are sensitive to moisture addition. Stratigraphic relationships between post-glacial terraces and soil analyses suggest a late Pleistocene (~13 - 11.5 ka) timing for slide initiation, a period coincident with high available moisture. Stream power analysis indicates that Holocene incision of the Gardiner River is focused at a knickpoint locally coincident with the toe of the active Slide Lake Landslide, providing a mechanism for modern, local reactivation of the ancient slides. Together, our findings broadly show how quantifying the temporal and spatial patterns of landslides can be diagnostic of the controls on slope failure, and can be used to understand risk. They also highlight the importance of careful site calibrations and bias removals in roughness analysis.Item Modeling mass balance at Robertson Glacier, Alberta, Canada 1912-2012(Montana State University - Bozeman, College of Letters & Science, 2017) Scanlon, Ryan Scott; Chairperson, Graduate Committee: Mark L. Skidmore; Jordy Hendrikx (co-chair)Glacier mass balance is important to study due to the role of glaciers in the hydrological cycle. Glacier mass balance is typically difficult to measure without numerous in situ measurements and monitoring over the course of many years. Physically based melt models are a good tool for estimating melt using temperature, solar radiation, and albedo and are used extensively in this thesis. A Degree Day (DD) model and an Enhanced Temperature Index (ETI) model are used to model mass balance for Robertson Glacier, Alberta, Canada during the period 1912-2012. The DD model only incorporates temperature, while the ETI model incorporates temperature, incoming solar radiation, and albedo. Incoming solar radiation was modeled for the period 2007-2012 and parameterized for the period 1912-2006 while temperature was measured at the regional scale and synthesized for Robertson Glacier and the snowpack thickness was modeled using PRISM. The DD and ETI models both assume a static ice mass, i.e. no flow or change in ice elevation due to mass loss over the century time period. Both models estimate a high value of annual and accumulated mean mass loss for the period 1912-2012. Sensitivity analyses of model inputs indicate that snowpack is an important factor, and it appears PRISM estimates may underrepresent beginning of the year snowpack by 220% based on a comparison of modelled to measured values on the adjacent Haig Glacier. Avalanching is not a key component of accumulation on the Haig Glacier but is a key process at Robertson Glacier, and could result in locally doubling the snowpack accumulation in avalanche zones. These factors including the resultant albedo changes with a thicker snowpack are all part of a compounding negative feedback cycle on glacier mass loss. In summary, the thesis has highlighted several potential limitations to the ETI and DD models for assessing mass loss for a small mountain glacier in the southern Canadian Rockies and provides suggestions for future modelling work in this region.Item Methane flux from recently exposed subglacial sediments, Robertson Glacier, Canada(Montana State University - Bozeman, College of Letters & Science, 2014) Spotts, Terra Marie; Chairperson, Graduate Committee: Mark L. SkidmoreMethane is over 20 times more effective than CO 2 as a greenhouse gas. Thus, its atmospheric concentration and the processes controlling it are important components of the global climate system. Recent research has shown methanogenesis in subglacial sediments. However, the net contribution from subglacial systems to the global methane budget is poorly understood due to a dearth of empirical data. Using measurements via the static chamber method, the flux of methane from recently exposed subglacial sediments at Robertson Glacier, Canadian Rockies was quantified. Methane concentrations were measured from surface gas flux chambers in transects both parallel and perpendicular to the glacier terminus. Over 300 measurements were made during the 2012 melt season (July to September) and used to determine both spatial and temporal variability in the gas fluxes. The chamber farthest from the glacier terminus, approximately 50 m down valley, had an average flux close to zero whereas the chambers nearest the terminus had the highest average fluxes. The average methane efflux from the sediment surface to atmosphere was 0.22 micromoles m -2 d -1. The highest methane efflux during the season, 11.0 micromoles m -2 d -1, was measured in close proximity to the glacier terminus. Shallow sediment cores were collected adjacent to the static chambers and vertical gas concentration profiles were measured from the cores. Within the profiles, methane concentrations were greater than atmospheric concentrations at all depths. Additionally, CO 2, CO and H 2 gas concentrations were analyzed in the cores to evaluate potential microbial metabolic pathways of methane production. Previous studies on methane fluxes from glacial sediments in Greenland and the Swiss Alps used single time point flux measurements during a melt season from multiple locations. This study concludes that such point measurements are unlikely representative for determining a net seasonal flux as they do not consider temporal variability. There was a two order of magnitude difference between the annual source contribution of methane based on the average melt season flux and the highest measured surface flux. This indicates that single sampling periods may significantly over or underestimate the net seasonal flux of methane from recently exposed glacial sediments to the atmosphere.Item Quaternary glacial geology and geomorphology of the Teton drainage area, Teton County, Montana(Montana State University - Bozeman, College of Letters & Science, 1968) Chalmers, Ann LeslieItem Late Pleistocene glacier dynamics of southwestern Montana and adjacent Idaho and paleoclimatic implications(Montana State University - Bozeman, College of Letters & Science, 1989) Murray, Donald R.