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Item Transient and steady state Rheo-NMR of shear banding wormlike micelles(Montana State University - Bozeman, College of Engineering, 2020) Al Kaby (Al Qayem), Rehab Noor; Chairperson, Graduate Committee: Sarah L. Codd and Jennifer Brown (co-chair); Jayesha S. Jayaratne, Timothy I. Brox, Sarah L. Codd, Joseph D. Seymour and Jennifer R. Brown were co-authors of the article, 'Rheo-NMR of transient and steady state shear banding under shear stratup' in the journal 'Journal of rheology' which is contained within this dissertation.; Sarah L. Codd, Joseph D. Seymour and Jennifer R. Brown were co-authors of the article, 'Characterization of velocity fluctuations and the transition from transient to steady state shear banding with and without pre-shear in a wormlike micelle solution under shear startup by Rheo-NMR' submitted to the journal 'Journal of applied rheology' which is contained within this dissertation.Over many years, the combination of nuclear magnetic resonance (NMR) techniques with rheometry, referred to as Rheo-NMR has been used to study materials under shear noninvasively. Rheo-NMR methods can provide valuable information on the rheological responses of materials or their behavior by temporally and spatially resolved mapping of the flow field. In this thesis, 1D velocity profiles across the fluid gap of a Couette shear cell are recorded using Rheo-NMR velocimetry to investigate the wormlike micelles (WLMs) surfactant system under transient and steady state flow conditions. The WLM system was a solution of 6 wt. % cetylpyridinium chloride (CPCl) and sodium salicylate (NaSal) in 0.5 M NaCl brine which is well-known for its ability to exhibit a mechanical response during flow known as shear banding. The shear banding phenomena is simply defined as the splitting of the flow into two macroscopic layers, a high and low shear band bearing different viscosities and local shear rates. Elastic instabilities are well known to develop in the unstable high shear band and manifest as fluctuations in the 1D measurements. Recently, it has been suggested that 1D velocimetry alone cannot reveal information about those observed fluctuations in terms of a sequence of elastic instabilities and 2D or 3D measurements are required. In this thesis, new Rheo-NMR equipment and quantitative analysis are used to characterize those fluctuations and show that 1D velocity measurements still have the potential to provide valuable information about 3D flows. Transient and steady state shear banding was observed for a range of shear rates across the stress plateau and the impact of several flow protocols were studied. The evolution of the high, low, and true shear rates, as well as interface position with time after shear startup was used to evaluate changes in the kinetics of shear band formation as a function of applied shear rate and flow protocol. Ultimately, these results will help in understanding the correlation between the macroscopic flow field and the microscopic structure and dynamics of WLMs and can also be a way to gain information about the presence and the dynamic of secondary flow without the need of a 3D measurement.Item Modeling the non-linear response of mixed culture biofilm structures to turbulent flow(Montana State University - Bozeman, College of Engineering, 2004) Towler, Brett William; Chairperson, Graduate Committee: Ladean McKittrick.Microbial biofouling of wetted interfaces can negatively impact the hydrodynamic performance of pressurized conduits. These impacts are due, in part, to the material properties of biofilm, yet few studies have examined this polymeric substance in the context of a constitutive relation. The goal of this research was two-fold; 1) to determine a suitable constitutive model for a mixed-culture biofilm and 2) use this material model in a numerical simulation to evaluate biofilm mechanical behavior in response to varying hydrodynamic conditions. Creep tests revealed that these biofilms may be classified as viscoelastic fluids. Furthermore, results indicated the presence of viscous, time-dependent and instantaneous components to the biofilm compliance functions. A regression analysis (r2 = 0.8819) supported the treatment of these samples as linear viscoelastic fluids within the stress range of 0.1 Pa to 0.5 Pa. A specific linear viscoelastic constitutive equation was then determined by fitting experimental results to analytical solutions using an optimization algorithm. It was found that the Burger material model closely approximated the behavior of all samples. A numerical fluid-structure interface model was then developed and employed in a parametric study to investigate biofilm behavior. The effect of the Burger material parameters, mean flow velocity and biofilm size were examined. Simulations showed that weaker or softer biofilms (characterized by lower elastic moduli) were highly susceptible to lift forces. Additionally, polar diagrams were generated by plotting the coefficients of drag versus lift. The plots suggested that in the first few seconds after loading, the deformation paths taken by hemispherical biofilms are largely insensitive to specific material coefficients. Moreover, the diagrams illustrated that the effects of biofilm strength, size and channel velocity on displacement were predictable. These relationships may lead to the development of a simple, yet accurate method for predicting the hydrodynamic forces acting on an attached biofilm.Item Quantifying the viscoelastic properties of treated and untreated Pseudomonas aeruginosa and Staphylococcus epidermidis biofilms using a rheological creep analysis(Montana State University - Bozeman, College of Engineering, 2008) Sutton, Michael Philip; Chairperson, Graduate Committee: Warren L. JonesMicrobial biofilms are quite difficult to kill and control, and present many problems to industry and medicine. The ability to alter the mechanical properties of biofilms could aid in the control of biofilm. The goal of this research project was to develop techniques for measuring the mechanical properties of biofilms so that the effects of chemical treatments could be assessed. Constitutive material models were developed and applied to assist in this effort to quantify the effects. Biofilms are viscoelastic in nature, therefore, rheological testing techniques were utilized for this research. Creep testing was performed on a parallel plate rheometer to determine biofilm mechanical properties. The rheometer is a mechanical device that can accurately measure and apply shear stress and strain on viscoelastic samples. The Burger material model closely approximated material behavior of most chemical treatments. This model was used for determining constitutive properties. Pseudomonas aeruginosa (FRD1) and Staphylococcus epidermidis colony biofilms were used for testing. Several treatment methods were used to investigate their effect on biofilm mechanical properties. As a source of different cations, solutions of NaCl, FeCl3, AlCl3, MgCl2, CaCl2, FeCl2 were used for testing. Multivalent cation treatments stiffened the FRD1 biofilm, but weakened the S. epidermidis. Urea treatments weakened both biofilm species. Glutaraldehyde treatments weakened the FRD1 biofilm, but had little effect on the S. epidermidis. Several treatments - EDTA, Barquat, chlorine, antibiotics (rifampin, and ciprofloxacin) - weakened biofilms of both species. The effect of the same chemical treatment between the two species of biofilm sometimes had nearly opposite effects on the biofilms mechanical properties. This research illustrated that it is possible to alter the mechanical properties of biofilm through chemical addition. Further, there are significant differences between the ways that the material properties of biofilms of different species of bacteria will be affected by a chemical treatment. Finally, it was observed that the 4-parameter Burger model for constitutive mechanical properties of biofilms fit the vast majority of the collected data, so that this model proves useful in comparing properties of biofilms grown or treated under various conditions.