Chien, R. R.Tu, Chi-ShunSchmidt, V. HugoWang, F.-T.2019-02-042019-02-042006R.R. Chien, C.-S. Tu, V.H. Schmidt, and F.-T. Wang, “Electric-field-induced and temperature‑induced phase transitions in high-strain ferroelectric Pb(Mg1/3Nb2/3)0.67Ti0.33O3 single crystal,” Journal of Physics: Condensed Matter 18, 8337-8344 (2006). doi: 10.1088/0953-8984/18/35/018.0953-8984https://scholarworks.montana.edu/handle/1/15213This work is to study electric (E)-field-induced and temperature-induced phase transitions in (001)-cut Pb(Mg1/3Nb2/3)0.67Ti0.33O3 (PMNT33%) single crystal, which are critical concerns for piezoelectric applications. Dielectric properties and domain structures (by polarizing microscope) are measured as functions of temperature and E field. The hysteresis loop of the polarization versus E field at room temperature is also measured. Without any E-field application, upon heating a first-order-type phase transition sequence rhombohedral (R) → rhombohedral/monoclinic/[001]tetragonal (R/M/T001) → cubic (C) takes place near 350 and 430 K, respectively. Under a dc E-field application along [001] at room temperature, [001] tetragonal (T001) phase domains are induced by various phase transition sequences, i.e. R → T001,R → M → T001, R → T → T001,andR→ M → T → T001,asthe E-field strength increases. In addition, E-field-induced microcracking is observed in this work.enThis Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).http://rightsstatements.org/vocab/InC/1.0/Electric-field-induced and temperature‑induced phase transitions in high-strain ferroelectric Pb(Mg1/3Nb2/3)0.67Ti0.33O3 single crystalArticle