Neufeldt, Sharon R.Russell, John E. A.2022-09-262022-09-262021-05Russell, J. E., & Neufeldt, S. R. (2021). C–O-Selective Cross-Coupling of Chlorinated Phenol Derivatives. Synlett, 32(15), 1484-1491.0936-5214https://scholarworks.montana.edu/handle/1/17229This is the accepted manuscript version of an article published by Georg Thieme Verlag [C–O-Selective Cross-Coupling of Chlorinated Phenol Derivatives. Synlett 32, 15 p1484-1491 (2021)] https://doi.org/10.1055/a-1503-6330Chemoselective cross-coupling of phenol derivatives is valuable for generating products that retain halides. Here we discuss recent developments in selective cross-couplings of chloroaryl phenol derivatives, with a particular focus on reactions of chloroaryl tosylates. The first example of a C–O-selective Ni-catalyzed Suzuki–Miyaura coupling of chloroaryl tosylates is discussed in detail.1 Introduction2 Density Functional Theory Studies on Oxidative Addition at Nickel(0)3 Stoichiometric Oxidative Addition Studies4 Development of a Tosylate-Selective Suzuki Coupling5 Conclusion and Outlooken-UScopyright Georg Thieme Verlag KG 2022https://perma.cc/9ZQS-7U3Wnickelcross-couplingoxidative addictionchemoselectivityArticle