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dc.contributor.authorPhongpreecha, Thanaphong
dc.contributor.authorChristy, Kendall F.
dc.contributor.authorSingh, Sandip K.
dc.contributor.authorHao, Pengchao
dc.contributor.authorHodge, David B.
dc.date.accessioned2022-02-03T17:33:33Z
dc.date.available2022-02-03T17:33:33Z
dc.date.issued2020-11
dc.identifier.citationPhongpreecha, Thanaphong, Kendall F. Christy, Sandip K. Singh, Pengchao Hao, and David B. Hodge. “Effect of Catalyst and Reaction Conditions on Aromatic Monomer Yields, Product Distribution, and Sugar Yields During Lignin Hydrogenolysis of Silver Birch Wood.” Bioresource Technology 316 (November 2020): 123907. doi:10.1016/j.biortech.2020.123907.en_US
dc.identifier.issn0960-8524
dc.identifier.urihttps://scholarworks.montana.edu/xmlui/handle/1/16621
dc.description.abstractThe impact of catalyst choice and reaction conditions during catalytic hydrogenolysis of silver birch biomass are assessed for their effect on aromatic monomer yields and selectivities, lignin removal, and sugar yields from enzymatic hydrolysis. At a reaction temperature of 220 °C with no supplemental H2, it was demonstrated that both Co/C and Ni/C exhibited aromatic monomer yields of >50%, which were close to the theoretical maximum expected for the lignin based on total β-O-4 content and exhibited high selectivities for 4-propylguaiacol and 4-propylsyringol. Pd/C exhibited a significantly different set of products, and using a model lignin dimer, showed a product profile that shifted upon inclusion of supplemental H2, suggesting that the generation of surface hydrogen is critical for this catalyst system. Lignin removal during hydrogenolysis could be correlated to glucose yields and inclusion of lignin depolymerizing catalysts significantly improves lignin removal and subsequent enzymatic hydrolysis yields.en_US
dc.language.isoen_USen_US
dc.rights© 2020 This manuscript version is made available under the CC-BY-NC-ND 4.0 license.en_US
dc.titleEffect of catalyst and reaction conditions on aromatic monomer yields, product distribution, and sugar yields during lignin hydrogenolysis of silver birch wooden_US
dc.typeArticleen_US
mus.citation.extentfirstpage123907en_US
mus.citation.journaltitleBioresource Technologyen_US
mus.citation.volume316en_US
mus.identifier.doi10.1016/j.biortech.2020.123907en_US
mus.relation.collegeCollege of Engineeringen_US
mus.relation.departmentChemical & Biological Engineering.en_US
mus.relation.universityMontana State University - Bozemanen_US
mus.data.thumbpage21en_US


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