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dc.contributor.authorNikolic, Marin
dc.contributor.authorDaemen, Luke
dc.contributor.authorRamirez-Cuesta, Anibal J.
dc.contributor.authorBalderas Xicohtencatl, Rafael
dc.contributor.authorCheng, Yongqiang
dc.contributor.authorPutnam, Seth T.
dc.contributor.authorStadie, Nicholas P.
dc.contributor.authorLiu, Xiaochun
dc.contributor.authorTerreni, Jasmin
dc.contributor.authorBorgschulte, Andreas
dc.identifier.citationNikolic, M., Daemen, L., Ramirez-Cuesta, A.J. et al. Neutron Insights into Sorption Enhanced Methanol Catalysis. Top Catal 64, 638–643 (2021).
dc.description.abstractSorption enhanced methanol production makes use of the equilibrium shift of the CO2 hydrogenation reaction towards the desired products. However, the increased complexity of the catalyst system leads to additional reactions and thus side products such as dimethyl ether, and complicates the analysis of the reaction mechanism. On the other hand, the unusually high concentration of intermediates and products in the sorbent facilitates the use of inelastic neutron scattering (INS) spectroscopy. Despite being a post-mortem method, the INS data revealed the change of the reaction path during sorption catalysis. Concretely, the experiments indicate that the varying water partial pressure due to the adsorption saturation of the zeolite sorbent influences the progress of the reaction steps in which water is involved. Experiments with model catalysts support the INS findings.en_US
dc.publisherSpringer Science and Business Media LLCen_US
dc.subjectsorption enhanced catalysisen_US
dc.subjectinelastic neutron scatteringen_US
dc.subjectCO2 hydrogenationen_US
dc.subjectdimethyl etheren_US
dc.titleNeutron Insights into Sorption Enhanced Methanol Catalysisen_US
mus.citation.journaltitleTopics in Catalysisen_US
mus.relation.collegeCollege of Letters & Scienceen_US
mus.relation.departmentChemistry & Biochemistry.en_US
mus.relation.universityMontana State University - Bozemanen_US

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