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dc.contributor.authorD'Andrilli, Juliana
dc.contributor.authorCooper, William T.
dc.contributor.authorForeman, Christine M.
dc.contributor.authorMarshall, Alan G.
dc.date.accessioned2016-02-06T00:21:11Z
dc.date.available2016-02-06T00:21:11Z
dc.date.issued2015-12
dc.identifier.citationD'Andrilli, Juliana, William T. Cooper, Christine M. Foreman, and Alan G. Marshall. "An ultrahigh-resolution mass spectrometry index to estimate natural organic matter lability." Rapid Communications in Mass Spectrometry 29, no. 24 (December 2015): 2385-2401. DOI:https://dx.doi.org/10.1002/rcm.7400.en_US
dc.identifier.issn0951-4198
dc.identifier.urihttps://scholarworks.montana.edu/xmlui/handle/1/9533
dc.description.abstractRationale: Determining the chemical constituents of natural organic matter (NOM) by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICRMS) remains the ultimate measure for probing its source material, evolution, and transport; however, lability and the fate of organic matter (OM) in the environment remain controversial. FTICRMS-derived elemental compositions are presented in this study to validate a new interpretative method to determine the extent of NOM lability from various environments. Methods: FTICRMS data collected over the last decade from the same 9.4 tesla instrument using negative electrospray ionization at the National High Magnetic Field Laboratory in Tallahassee, Florida, was used to validate the application of a NOM lability index. Solid-phase extraction cartridges were used to isolate the NOM prior to FTICRMS; mass spectral peaks were calibrated internally by commonly identified NOM homologous series, and molecular formulae were determined for NOM composition and lability analysis. Results: A molecular lability boundary (MLB) was developed from the FTICRMS molecular data, visualized from van Krevelen diagrams, dividing the data into more and less labile constituents. NOM constituents above the MLB at H/C ≥1.5 correspond to more labile material, whereas NOM constituents below the MLB, H/C <1.5, exhibit less labile, more recalcitrant character. Of all marine, freshwater, and glacial environments considered for this study, glacial ecosystems were calculated to contain the most labile OM. Conclusions: The MLB extends our interpretation of FTICRMS NOM molecular data to include a metric of lability, and generally ranked the OM environments from most to least labile as glacial > marine > freshwater. Applying the MLB is useful not only for individual NOM FTICRMS studies, but also provides a lability threshold to compare and contrast molecular data with other FTICRMS instruments that survey NOM from around the world.en_US
dc.description.sponsorshipNSF Division of Materials Research through DMR-11-57490en_US
dc.rightsCC BY 4.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en_US
dc.titleAn ultrahigh-resolution mass spectrometry index to estimate natural organic matter labilityen_US
dc.typeArticleen_US
mus.citation.extentfirstpage2385en_US
mus.citation.extentlastpage2401en_US
mus.citation.issue24en_US
mus.citation.journaltitleRapid Communications in Mass Spectrometryen_US
mus.citation.volume29en_US
mus.identifier.categoryEngineering & Computer Scienceen_US
mus.identifier.doi10.1002/rcm.7400en_US
mus.relation.collegeCollege of Engineeringen_US
mus.relation.departmentCenter for Biofilm Engineering.en_US
mus.relation.departmentChemical & Biological Engineering.en_US
mus.relation.universityMontana State University - Bozemanen_US
mus.data.thumbpage9en_US
mus.contributor.orcidForeman, Christine M.|0000-0003-0230-4692en_US


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