Browsing by Author "Ding, Y."

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Dielectric permittivity and magnetoelectric coupling in multiferroic BiFeO3 and (Bi0.95La0.05)FeO3 ceramics
(2011) Tu, Chi-Shun; Ding, Y.; Yang, W.-C.; Wang, T.-H.; Chien, R. R.; Schmidt, V. Hugo; Yao, Y.-D.; Wu, K.-T.
Dielectric permittivity and loss of BiFeO 3 (BFO) and 5 mol% lanthanum-substituted BFO [(Bi 0.95 La 0.05 )FeO 3 or BFO-5% La] ceramics have been carried out as functions of temperature and frequency. A frequency-dependent and broad dielectric shoulder and maximum were observed in BFO and BFO-5% La near 600-700 K. These dielectric responses are likely due to the magnetoelectric coupling while the antiferromagnetic-paramagnetic transition takes place near the Néel temperature. As an approximation, a barrier model with intrinsic barriers B (in temperature unit) every lattice constant a and extrinsic barriers B +Δ every distance d is introduced to describe the low-frequency upturn in dielectric loss in the high-temperature region. Good qualitative fits are obtained for BFO and BFO-5% La. This work suggests that 5 mol% La substitution can enhance dielectric response and considerably reduce electric conductivity.
Magnetoelectric coupling and phase transition in BiFeO3 and (BiFeO3)0.95(BaTiO3)0.05 ceramics
(2011) Wang, T.-H.; Tu, Chi-Shun; Chen, H.-Y.; Ding, Y.; Lin, T.C.; Yao, Y.-D.; Schmidt, V. Hugo; Wu, K.-T.
In situ high-resolution synchrotron x-ray diffraction reveals a local minimum in rhombohedral distortion angle α R (associated with an inflection in the lattice constantaR ) near 400 and 350 °C in BiFeO3 (BFO) and (BiFeO3)0.95(BaTiO3)0.05 (BFO–5%BT), respectively. It suggests a coupling between ferroelectric and magnetic parameters near the antiferromagnetic–paramagnetic transition, which is responsible for the broad frequency-dependent dielectric maxima. A rhombohedral (R)–orthorhombic (O)–cubic (C) transition sequence takes place near 820 and 850 °C in BFO upon heating. BFO–5%BT exhibits a R–C transition near 830 °C. The BaTiO3 substitution can enhance dielectric and ferromagnetic responses and reduce electric leakage. The dielectric loss of BFO–5%BT remains less than 0.04 below 150 °C.
Structural and dielectric properties of (Bi 1-x Ba x )(Fe 1-x Ti x )O 3 multiferroic ceramics
(2014) Wang, T.-H.; Tu, Chi-Shun; Schmidt, V. Hugo; Chien, R. R.; Ding, Y.
Phase transitions, dielectric permittivity, and conductivity of (Bi1-xBax)(Fe1-xTix)O3 (x = 0.05 and 0.1) [BFO-(Ba,Ti)] multiferroic ceramics have been studied as functions of temperature and frequency. In situ synchrotron x-ray diffraction revealed rhombohedral–cubic transitions in the temperature ranges 760–780°C in BFO-5%(Ba,Ti), and 720–750°C in BFO-10%(Ba,Ti). A one-dimensional barrier model with intrinsic barriers B every lattice constant a and extrinsic barriers B + Δ is introduced to describe the dielectric response and conductivity. This work revealed that (Ba,Ti) substitutions can enhance the intrinsic barriers and reduce the hopping rate of charge carriers, thereby giving the desired effect of decreasing the conductivity.