Browsing by Author "Wei, Dandan"

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Downward transport of ozone rich air & implications for atmospheric chemistry in the Amazon rainforest
(2016-01) Gerken, Tobias; Wei, Dandan; Chase, Randy J.; Fuentes, Jose D.; Schumacher, Courtney; Machado, Luiz A.; Andreoli, Rita V.; Chamecki, Marcelo; Ferreira de Souza, Rodrigo A.; Freire, Livia S.; Jardine, Angela B.; Manzi, Antonio O.; Nascimento dos Santos, Rosa M.; von Randow, Celso; dos Santos Costa, Patricia; Stoy, Paul C.; Tota, Julio; Trowbridge, Amy M.
From April 2014 to January 2015, ozone (O3) dynamics were investigated as part of GoAmazon 2014/5 project in the central Amazon rainforest of Brazil. Just above the forest canopy, maximum hourly O3 mixing ratios averaged 20 ppbv (parts per billion on a volume basis) during the June–September dry months and 15 ppbv during the wet months. Ozone levels occasionally exceeded 75 ppbv in response to influences from biomass burning and regional air pollution. Individual convective storms transported O3-rich air parcels from the mid-troposphere to the surface and abruptly enhanced the regional atmospheric boundary layer by as much as 25 ppbv. In contrast to the individual storms, days with multiple convective systems produced successive, cumulative ground-level O3 increases. The magnitude of O3 enhancements depended on the vertical distribution of O3 within storm downdrafts and origin of downdrafts in the troposphere. Ozone mixing ratios remained enhanced for > 2 h following the passage of storms, which enhanced chemical processing of rainforest-emitted isoprene and monoterpenes. Reactions of isoprene and monoterpenes with O3 are modeled to generate maximum hydroxyl radical formation rates of 6 × 106 radicals cm−3s−1. Therefore, one key conclusion of the present study is that downdrafts of convective storms are estimated to transport enough O3 to the surface to initiate a series of reactions that reduce the lifetimes of rainforest-emitted hydrocarbons.
Environmental and biological controls on seasonal patterns of isoprene above a rain forest in central Amazonia
(2018-06) Wei, Dandan; Fuentes, Jose D.; Gerken, Tobias; Chamecki, Marcelo; Trowbridge, Amy M.; Stoy, Paul C.; Katul, Gabriel G.; Fisch, Gilberto; Acevedo, Otavio; Manzi, Antonio O.; Randow, Celso von; Nascimento dos Santos, Rosa Maria
The Amazon rain forest is a major global isoprene source, but little is known about its seasonal ambient concentration patterns. To investigate the environmental and phenological controls over isoprene seasonality, we measured isoprene mixing ratios, concurrent meteorological data, and leaf area indices from April 2014 to January 2015 above a rain forest in the central Amazon, Brazil. Daytime median isoprene mixing ratios varied throughout the year by a factor of two. The isoprene seasonal pattern was not solely driven by sunlight and temperature. Leaf age and quantity also contributed to the seasonal variations of isoprene concentrations, suggesting leaf phenology was a crucial variable needed to correctly estimate isoprene emissions. A zero-dimensional model incorporating the estimated emissions, atmospheric boundary layer dynamics, and air chemistry was used to assess the contributions of each process on the variability of isoprene. Surface deposition was an important sink mechanism and accounted for 78% of the nighttime loss of isoprene. Also, chemical reactions destroyed isoprene and during 6:00 to 18:00 h local time 56, 77, 69, and 69% of the emitted isoprene was chemically consumed in June, September, December, and January, respectively. Entrainment fluxes from the residual layer contributed 34% to the early-morning above-canopy isoprene mixing ratios. Sensitivity analysis showed that hydroxyl radical (HO) recycling and segregation of isoprene–HO played relatively lesser roles (up to 16%) in regulating ambient isoprene levels. Nitric oxide (NO) levels dominated isoprene chemical reaction pathways associated with consumption and production of HO under low-NO and high volatile organic compound (VOC) conditions. While surface deposition and oxidative processes altered isoprene levels, the relative importance of these factors varied seasonally with leaf phenology playing a more important role.