Theses and Dissertations at Montana State University (MSU)
Permanent URI for this collectionhttps://scholarworks.montana.edu/handle/1/733
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Item Daily signals in nitrate processing provide a holistic perspective on stream corridor hydrologic and biogeochemical function(Montana State University - Bozeman, College of Agriculture, 2023) Foster, Madison Jo; Chairperson, Graduate Committee: Robert A. Payn; This is a manuscript style paper that includes co-authored chapters.Understanding interactive pathways of biogeochemical reaction and water movement in stream corridors is critical given the role stream corridors play in mitigating nitrate loading from agricultural watersheds. However, few studies consider the interactive effects of nitrate loading, riparian processing, and stream ecosystem processing, which may limit abilities to predict downstream nitrate delivery. Riparian groundwater inputs and stream ecosystem processing may vary due to daily cycles in evapotranspiration or stream ecosystem primary production. Recent advances in high-frequency monitoring of stream chemistry throughout the day exhibit potential to explore both hydrologic and biogeochemical influences on nitrate attenuation. In this thesis, I explore how diel variations in stream reach nitrate processing can provide holistic perspectives on the attenuation of nitrate along stream corridors within a watershed that is heavily influenced by agricultural land use. Nitrate processing is defined as the evident changes in nitrate concentration in parcels of water as they travel along a given reach of a stream, as measured from nitrate sensors located at the head and base of ca. 0.5 km reaches. To understand controls on diel variation in nitrate processing, we measured diel processing signals in agricultural headwater reaches in Central Montana, USA spanning variable atmospheric and flow conditions from March through August in 2020-2022. Across 168 days with valid data, most signals exhibited little diel variation (n = 106) and this lack of variation occurred most frequently during cooler and shorter days. In contrast, signals with greater variation were common during longer days, warmer temperatures, and lower flows (n = 62). This seasonal shift in patterns suggests that solar radiation and stream flow are primary controls on diel nitrate processing signals in these low-order reaches. In addition to diel variation, less overall nitrate attenuation in the study reach with direct inputs of high-nitrate upland waters suggest that the degree of hydrologic connection to upland aquifers influences apparent reach nitrate processing. This work highlights how understanding the drivers of diel processing signals may lead to a more holistic understanding of how multiple interacting processes in stream corridors influence nitrate delivery to downstream ecosystems.Item Spatial patterns in soil depth and implications for offseason nitrogen dynamics in dryland wheat systems of central Montana(Montana State University - Bozeman, College of Agriculture, 2022) Fordyce, Simon Isaac; Co-chairs, Graduate Committee: Clain Jones and Craig Carr; Pat Carr, Clain Jones, Jed Eberly, Scott Powell, Adam Sigler and Stephanie Ewing were co-authors of the article, 'Exploring relationships between soil depth and multi-temporal spectral reflectance in a semi-arid agroecosystem: effects of spatial and temporal resolution' submitted to the journal 'Remote Sensing of environment' which is contained within this thesis.; Pat Carr, Clain Jones, Jed Eberly, Rob Payn, Adam Sigler and Stephanie Ewing were co-authors of the article, 'Spatiotemporal patterns of nitrogen mineralization in a dryland wheat system' submitted to the journal 'Agriculture, ecosystems, and environment' which is contained within this thesis.Shallow soils (< 50 cm) under dryland wheat (Triticum aestivum L.) production lose large amounts of inorganic nitrogen (N) to leaching. Crops grown in shallow soils may be more responsive to N fertilizer due to lower fertilizer recovery and suppressed mineralization, raising questions as to whether standard practices of N fertilizer rate determination can increase risks of leaching and groundwater contamination in these environments. Mineralized N can be a major nutritional supplement for wheat crops in dryland agroecosystems, so accurate estimates of mineralization inputs can have important economic and environmental implications. To assess the potential for suppressed N mineralization in shallow soils, we used spectral reflectance from up to three sensors (unmanned aerial vehicle, National Agricultural Imagery Program, and Sentinel 2) to spatially characterize soil depth on three fields in Central Montana (Chapter 2) and compared surface (0-20 cm) carbon and N cycling indices across soil depth classes (Chapter 3). Carbon dynamics were stable across depth classes while N mineralization was lower in the shallow class. Results confirm multispectral imagery as a valuable tool for non-destructively characterizing fine-scale spatial patterns in soil depth and corroborate previous findings of lower N mineralization in shallow soil environments. Given the potential for heightened fertilizer responsiveness due to lower mineralization in these environments, decision support systems for site-specific fertility management (e.g., variable rate fertilizer application) should assess the environmental consequences of leaching alongside the economic benefits of applied fertilizer rates which maximize responses of yield, quality and same-year net revenue.Item Effect of summer fallowing, perennial crop cover and conservation reserve practices on soil nitrate distribution(Montana State University - Bozeman, College of Agriculture, 1994) Pannebakker, Lynn S.; Chairperson, Graduate Committee: Jim BauderDryland agriculture is an economically feasible method of producing crops in some parts of the semi-arid regions of the mid-west and western United States. Summer fallowing, which is commonly practiced in these regions, serves to replenish soil moisture and plant-available nitrate-nitrogen (N0 3--N), while also stabilizing production and more uniformly distributing the work load. In areas where dryland agriculture is concentrated, summer fallowing may lead to N0 3--N contamination of ground-water due to lack of plant uptake of excess water and N. Under certain conditions of precipitation, soil percolation, slope, and cropping intensity, summer fallowing has been shown to cause elevated N03--N concentrations in shallow groundwater wells. These elevated N0 3--N levels have been detected in several areas of the U.S. Two areas where high N0 3--N concentrations have been repeatedly found in groundwater samples are in northeastern and central Montana. Judith Basin and Fergus Counties of Montana were selected for soil sampling to assess any differences in soil NO3--N concentrations under three different land use systems: 1) crop fallow rotation, 2) acreage enrolled in the USDA Agricultural Stabilization and Conservation Service (ASCS) conservation reserve program (CRP), 3) and rangeland. Soil samples were collected to a depth of three m (10 ft) at four different sites in each county. Soil samples from all sampling depths at each of the eight sites were analyzed for gravel percent (>2 mm diameter) , N0 3--N load, and N0 3--N concentration. Samples from 0 m to 0.6 m were also analyzed for total-N concentration. Trends in soil N0 3-N give evidence that summer fallowing may be the cause of N0 3--N in shallow groundwater in some areas Of Montana where dryland cropping is practiced. Overall, average soil N0 3--N concentration throughout the sampled soil profile was 4.2, 2.0, and 1.3 mgkg-1 for the crop fallow, CRP, and rangeland land use practices, respectively. Average N0 3--N concentration in Fergus County ranged from 2.5 mgkg-1 to 20.4 mgkg-1 under crop fallow while it ranged from only 0.9 to 6.2 mgkg-1 and from 0.9 to 4.2 mgkg-1 for the CRP and rangeland uses, respectively. Average N0 3--N concentration in Judith Basin County ranged from 1.4 mgkg-1 to 6.9 mgkg-1, 0.6 mgkg-1 to 2.0 mgkg-1, and from 0.8 mgkg-1 to 1.4 mgkg-1 under crop fallow, CRP, and rangeland land use systems, respectively. Assuming that extensive use of crop fallow causes increased N0 3--N concentrations under some conditions, alternative land use management practices may be effective in reducing N0 3--N levels in such areas.