Theses and Dissertations at Montana State University (MSU)
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Item Daily signals in nitrate processing provide a holistic perspective on stream corridor hydrologic and biogeochemical function(Montana State University - Bozeman, College of Agriculture, 2023) Foster, Madison Jo; Chairperson, Graduate Committee: Robert A. Payn; This is a manuscript style paper that includes co-authored chapters.Understanding interactive pathways of biogeochemical reaction and water movement in stream corridors is critical given the role stream corridors play in mitigating nitrate loading from agricultural watersheds. However, few studies consider the interactive effects of nitrate loading, riparian processing, and stream ecosystem processing, which may limit abilities to predict downstream nitrate delivery. Riparian groundwater inputs and stream ecosystem processing may vary due to daily cycles in evapotranspiration or stream ecosystem primary production. Recent advances in high-frequency monitoring of stream chemistry throughout the day exhibit potential to explore both hydrologic and biogeochemical influences on nitrate attenuation. In this thesis, I explore how diel variations in stream reach nitrate processing can provide holistic perspectives on the attenuation of nitrate along stream corridors within a watershed that is heavily influenced by agricultural land use. Nitrate processing is defined as the evident changes in nitrate concentration in parcels of water as they travel along a given reach of a stream, as measured from nitrate sensors located at the head and base of ca. 0.5 km reaches. To understand controls on diel variation in nitrate processing, we measured diel processing signals in agricultural headwater reaches in Central Montana, USA spanning variable atmospheric and flow conditions from March through August in 2020-2022. Across 168 days with valid data, most signals exhibited little diel variation (n = 106) and this lack of variation occurred most frequently during cooler and shorter days. In contrast, signals with greater variation were common during longer days, warmer temperatures, and lower flows (n = 62). This seasonal shift in patterns suggests that solar radiation and stream flow are primary controls on diel nitrate processing signals in these low-order reaches. In addition to diel variation, less overall nitrate attenuation in the study reach with direct inputs of high-nitrate upland waters suggest that the degree of hydrologic connection to upland aquifers influences apparent reach nitrate processing. This work highlights how understanding the drivers of diel processing signals may lead to a more holistic understanding of how multiple interacting processes in stream corridors influence nitrate delivery to downstream ecosystems.Item Fallow replacement and alternative fertilizer practices : effects on nitrate leaching, grain yield and protein, and net revenue in a semiarid region(Montana State University - Bozeman, College of Agriculture, 2015) John, Andrew Augustus; Chairperson, Graduate Committee: Clain JonesHigh nitrate concentrations in groundwater have been observed in agricultural regions worldwide. In the Judith River Watershed of central Montana, groundwater nitrate concentrations have increased from 10 to 23 mg L-1 over the span of 20 years. Nitrate leaching from agricultural fields is a major concern for growers and stakeholders in the region. Little research has been conducted in dryland semiarid regions on the effects of agricultural practices on nitrate leaching. We conducted a 2-yr study comparing three alternative management practices (pea rotation, controlled-release urea, split nitrogen application) to grower standard practices (fallow, conventional urea, spring broadcast urea) on grain yield, grain protein, net revenue, and the amount of nitrate leached. Eight field treatment interfaces were established across three farms and each treatment was in duplicate per year. Ten soil and biomass sampling locations were designated on both sides of the interface. Net revenue was calculated by enterprise budgets constructed from local and state data. Nitrate leaching was calculated using a nitrogen mass balance equation. Replacing pea with fallow decreased winter wheat grain yield and protein yet had no effect on net revenue during the first year of the study (2013). In the second year, pea-winter wheat earned $83 ha -1 more (P<0.1) than fallow-winter wheat. Neither fertilizer alternative management practice had an effect on net revenue. In the 2013 treatment year, wheat after pea leached less nitrate (20 kg N ha -1) than wheat after fallow (56 kg N ha -1), indicating more deep percolation of nitrate with fallow practice. In the 2014 treatment year, a greater amount of nitrate leached (P<0.1) while using controlled-release urea than conventional urea, possibly in part because the controlled release urea was applied earlier than conventional urea. The results of our study revealed that replacing fallow with pea can decrease the amount of nitrate that leaches out of the root zone. Also, this practice either increased or had no effect on net revenue, revealing its ability to be economically feasible for a grower to implement. Based on our findings, future research should likely focus on practices that decrease rates of deep percolation.Item Groundwater nitrate transport and residence time in a vulnerable aquifer under dryland cereal production(Montana State University - Bozeman, College of Agriculture, 2013) Miller, Christine Ross; Chairperson, Graduate Committee: Stephanie A. Ewing; Stephanie A. Ewing, W. Adam Sigler, E. N. J. Brookshire, Clain A. Jones, Douglas Jackson-Smith and Gary S. Weissmann were co-authors of the article, 'Groundwater nitrate transport and residence time in a vulnerable aquifer under dryland cereal production' submitted to the journal 'Journal of geophysical research - biogeosciences' which is contained within this thesis.Selection of agricultural management practices to reduce nitrate leaching from soils can only be successful if both nitrate loading rates from soils to shallow aquifers and groundwater residence times are quantified. Elevated nitrate concentrations in shallow unconfined aquifers are commonly observed in agricultural areas as a result of increased N inputs. In the Judith River Watershed (JRW) in central Montana, USA, notably high nitrate concentrations in groundwater and stream water have exceeded the U.S. EPA drinking water standard of 10 mg L -1 for at least two decades. This large (24,400 ha) watershed drains immediately into the Missouri River, a tributary of the Mississippi River. Over an eleven month period in 2012, we measured groundwater and surface water nitrate concentrations across a hydrologically isolated strath terrace. We use the resulting data to constrain nitrate accumulation dynamics in the shallow aquifer. Nitrate is relatively conservative in this location, as it is high in groundwater (17.57 +/- 4.29 mg L -1; all groundwater samples pooled together), and remains high in streams and springs that drain the landform (15.67 +/- 9.45 mg L -1; all surface water and spring samples pooled together). We use a numerical model to simulate the character of nitrate accumulation in the aquifer as a whole, in order to evaluate how the entire period of cultivation has contributed to current nitrate concentrations, and begin to predict response times for effects of land use change. We consider the effect of groundwater residence time and travel time on nitrate loading using particle tracking in a three dimensional model aquifer. We find no correlation with nitrate concentrations in groundwater and emerging surface waters, and suggest approaches for improving both the geometry of the model and the selection of sites in future work. Overall, our results imply that groundwater residence times are several decades at most, suggesting that similar timeframes will be needed to reduce overall nitrate concentrations in groundwater and emergent streams to below drinking water standards. Preliminary evaluation of several management scenarios suggests that both increased fertilizer use efficiency and rotational strategies may be needed to prevent the loss of soil N to groundwater.Item Effect of summer fallowing, perennial crop cover and conservation reserve practices on soil nitrate distribution(Montana State University - Bozeman, College of Agriculture, 1994) Pannebakker, Lynn S.; Chairperson, Graduate Committee: Jim BauderDryland agriculture is an economically feasible method of producing crops in some parts of the semi-arid regions of the mid-west and western United States. Summer fallowing, which is commonly practiced in these regions, serves to replenish soil moisture and plant-available nitrate-nitrogen (N0 3--N), while also stabilizing production and more uniformly distributing the work load. In areas where dryland agriculture is concentrated, summer fallowing may lead to N0 3--N contamination of ground-water due to lack of plant uptake of excess water and N. Under certain conditions of precipitation, soil percolation, slope, and cropping intensity, summer fallowing has been shown to cause elevated N03--N concentrations in shallow groundwater wells. These elevated N0 3--N levels have been detected in several areas of the U.S. Two areas where high N0 3--N concentrations have been repeatedly found in groundwater samples are in northeastern and central Montana. Judith Basin and Fergus Counties of Montana were selected for soil sampling to assess any differences in soil NO3--N concentrations under three different land use systems: 1) crop fallow rotation, 2) acreage enrolled in the USDA Agricultural Stabilization and Conservation Service (ASCS) conservation reserve program (CRP), 3) and rangeland. Soil samples were collected to a depth of three m (10 ft) at four different sites in each county. Soil samples from all sampling depths at each of the eight sites were analyzed for gravel percent (>2 mm diameter) , N0 3--N load, and N0 3--N concentration. Samples from 0 m to 0.6 m were also analyzed for total-N concentration. Trends in soil N0 3-N give evidence that summer fallowing may be the cause of N0 3--N in shallow groundwater in some areas Of Montana where dryland cropping is practiced. Overall, average soil N0 3--N concentration throughout the sampled soil profile was 4.2, 2.0, and 1.3 mgkg-1 for the crop fallow, CRP, and rangeland land use practices, respectively. Average N0 3--N concentration in Fergus County ranged from 2.5 mgkg-1 to 20.4 mgkg-1 under crop fallow while it ranged from only 0.9 to 6.2 mgkg-1 and from 0.9 to 4.2 mgkg-1 for the CRP and rangeland uses, respectively. Average N0 3--N concentration in Judith Basin County ranged from 1.4 mgkg-1 to 6.9 mgkg-1, 0.6 mgkg-1 to 2.0 mgkg-1, and from 0.8 mgkg-1 to 1.4 mgkg-1 under crop fallow, CRP, and rangeland land use systems, respectively. Assuming that extensive use of crop fallow causes increased N0 3--N concentrations under some conditions, alternative land use management practices may be effective in reducing N0 3--N levels in such areas.Item Encapsulated mixed-bed ion-exchange resins : practical uses monitoring nitrate movement and nitrogen soil fertility(Montana State University - Bozeman, College of Agriculture, 1997) Miller, John HowardItem Soil and terrain attributes for evaluation of leaching in a Montana farm field(Montana State University - Bozeman, College of Agriculture, 1995) Landon, Melissa Ann