Theses and Dissertations at Montana State University (MSU)
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Item Understanding the effects of floodplain shade on hyporheic and stream channel temperature cycles(Montana State University - Bozeman, College of Agriculture, 2024) Fogg, Sarah Kathleen; Chairperson, Graduate Committee: Geoffrey C. Poole; This is a manuscript style paper that includes co-authored chapters.River reaches with coarse-grained alluvial floodplains have a breadth of lateral interaction between the channel and surrounding landscape, yielding extensive riparian zones and high rates of gross water exchange between the channel and substrate (i.e., hyporheic exchange). The lateral hyporheic zone on floodplain rivers is often near the ground surface, allowing for heat exchange between the atmosphere, unsaturated sediments, and hyporheic zone. We hypothesized that floodplain shade overlying lateral hyporheic water influences the conductive heat flux through unsaturated sediments, thus influencing hyporheic temperatures and temperatures in associated stream channels. We conducted simulation modeling experiments to test the potential effects of floodplain shade on hyporheic and stream channel temperatures. We found that scenarios with floodplain shade led to cooler hyporheic and stream temperatures than scenarios lacking floodplain shade under a variety of realistic floodplain conditions. We conclude that floodplain forest shade is a novel consideration for riparian management on floodplain river reaches and may be crucial in managing and maintaining cold-water habitat into the future.Item Thermalization and exciton localization in 2D semiconductors(Montana State University - Bozeman, College of Letters & Science, 2023) Strasbourg, Matthew Christopher; Chairperson, Graduate Committee: Nick Borys; This is a manuscript style paper that includes co-authored chapters.2D semiconductors are a promising class of materials to investigate for applications in the next generation of photonic devices. They can be used to generate quantum light and also exhibit correlated many-body phenomena. Many of the novel optoelectronic properties of 2D semiconductors are associated with strongly-bound hydrogen-like states known as excitons. Excitons in 2D semiconductors have binding energies on the order of 100s of meV and are stable at room temperature. At low temperatures, higher-order excitonic states such as charged excitons and biexcitons--multiple-bound excitons that are like hydrogen molecules-- and localized excitons that emit quantum light are also observed. Whether excited optically or electronically, a diversity of high-energy excitons and free carriers are produced directly after excitation. The relaxation and thermalization of these initial states influence the formation of excitons, biexcitons, and localized excitons. Here, I present work that (i) investigates the thermalization of excited states in a prototypical 2D semiconductor, monolayer (1L-) WSe2, and reports the discovery that the generation of charged biexcitons is enhanced with increasing photoexcitation energy, (ii) shows the emergence of quantum emitters (QEs) in a new 2D QE platform: 1L-WSe2 nanowrinkle arrays induced by Au nano stressors, and (iii) uses a novel method to classify the excited-state dynamics of 2D QEs and differentiate emitter populations. A suite of low-temperature energy- and time- resolved optical spectroscopies are used to conduct this work. This work shows how excited state thermalization affects the formation of exciton and biexcitons and investigates the optical properties of an emergent class of 2D quantum light emitters.Item Experimental evaluation of the mechanical properties of recycled high-density polyethylene (rHDPE) blended with talc filler, for engineering applications(Montana State University - Bozeman, College of Engineering, 2023) Malyuta, Daniel Aaron Isilyumu; Chairperson, Graduate Committee: Kirsten Matteson; This is a manuscript style paper that includes co-authored chapters.The extensive use of thermoplastic products, particularly high-density polyethylene (HDPE), has led to significant plastic waste, posing environmental threats. To manage thermoplastic waste, recycling is the preferred method; however, this has not been wholly effective due to technological and economic challenges and limitations. Large-scale applications of recycled HDPE (rHDPE) can incentivize recycling and create new revenue streams. HDPE is a well-established thermoplastic for engineering applications, and components made of HDPE have desirable properties such as high strength-to-weight ratio, ease of processing, availability, low cost, and excellent chemical and corrosion resistance. With concerns about the fate of plastics at end-of-life, there is a growing interest in strategies to utilize rHDPE in place of virgin HDPE (vHDPE). This study focused on investigating the mechanical and thermal properties of rHDPE-talc blends across various talc filler contents and temperatures, and across four recycling generations, as understanding these properties is crucial for application. Following ASTM standards, tests for tensile strength, elastic modulus, storage modulus, nominal yield stiffness, nominal yield strain, impact strength, and melt flow index were performed. Dynamic mechanical analysis and differential scanning calorimetry were also carried out. Results show that talc content and temperature affect tensile strength, elastic modulus, nominal stiffness, yield strain, impact strength, and storage modulus. Melting temperature decreased while crystallinity increased with talc filler content increase. Compared to neat HDPE and in most cases vHDPE-talc blends, rHDPE-talc blends perform better. Response Surface Methodology was applied using the Central Composite Design statistical experimental design approach to further study the stiffness and strength of rHDPE as functions of temperature and talc filler content. It revealed significant correlations for practical applications. Increasing the number of thermal reprocessing cycles decreased tensile strength, elastic modulus, impact strength, and storage modulus, while nominal yield strain and melt flow index increased. Crystallinity and melting temperature minimally decreased with increased thermal reprocessing cycles. Despite these changes, most of the properties of both the neat rHDPE and its talc blends remain comparable to the virgin counterparts, even after the fourth recycling generation. This implies that the recycled materials can be suitable for use in existing applications of vHDPE.Item Studying high pressure monopropellant combustion with operando optical spectroscocpy: nitromethane -- a case study(Montana State University - Bozeman, College of Letters & Science, 2022) Sinrud, Joshua Basil; Chairperson, Graduate Committee: Robert Walker; This is a manuscript style paper that includes co-authored chapters.High pressure monopropellant combustion mechanisms are traditionally difficult to validate, due to difficulties associated with maintaining stable flames and measuring intermediates in situ. We have recently developed a continuous feed, liquid-propellant strand burner assembly capable of sustaining stable monopropellant flames in inert atmospheres up to 80 bar for more than 30 minutes. The assembly is housed in a high-pressure chamber that has optical access for observing the flame. With an ultimate goal of assessing combustion mechanisms for complex, monopropellant fuel mixtures, the strand burner and chamber were tested using a simple monopropellant, nitromethane (NM) in both inert and oxidizing atmospheres. Detailed NM combustion mechanisms are well developed, although most are based on data from studies at lower pressures (< or =10 bar) where only bipropellant (in air) combustion is feasible. Models provide strong -- but unverified -- evidence that NM combustion mechanisms depend sensitively on pressure and the relevant mechanisms are expected to change depending on whether NM combusts under mono- or bipropellant conditions. Optical emission from NM flames was directed onto a spectrograph/CCD assembly to show a rich collection of well- resolved, rovibrational lines having linewidths on the order of 3-4 wavenumbers (cm -1). Of particular interest were features between 14,500 cm -1 (690 nm) and 13,000 cm -1 (769 nm) assigned to rovibrational transitions from the H2O (3,0,1) vibrational state relaxing to the ground state. Spectra also showed clear evidence of OH* emission from the electronic (A-X) transition. Together with ex situ measurements of combustion exhaust, these data are being used to identify specific NM combustion pathways. The first ever spatially resolved 1D spectral and 2D chemiluminescence images for both intermediates and products allows direct comparison of relative species concentration and allows juxtaposition of experimental data with simulated speciation data for mechanism validation. Furthermore, temperature profiles were calculated for bipropellant flames using 1D spectral images of rotationally resolved OH* (A-X) transitions and compared to simulated speciation data based on previously proposed combustion mechanisms. These results are some of the first experimental data capable of directly evaluating the validity of proposed high-pressure nitromethane combustion mechanisms.Item Improving pH and temperature stability of urease for ureolysis-induced calcium carbonate precipitation(Montana State University - Bozeman, College of Engineering, 2022) Akyel, Arda; Chairperson, Graduate Committee: Robin Gerlach and Adrienne Phillips (co-chair); This is a manuscript style paper that includes co-authored chapters.Ureolysis-induced calcium carbonate (CaCO 3) precipitation (UICP) is a promising technology that takes advantage of urea hydrolysis. During UICP, the enzyme urease hydrolyzes urea, and calcium carbonate can precipitate in the presence of calcium (Ca 2+). This process is also known as biomineralization, and urease is found in several bacterial and plant cells. Urease must be active to enable biomineralization engineering applications such as sealing leakage pathways around wells for CO 2 sequestration. However, biotechnological reactions are limited by physicochemical conditions (temperature, pH, toxic compounds, etc.), and conditions in practice can be suboptimal. Sporosarcina pasteurii and jack bean meal (JBM) ureolytic activities were investigated while simulating potential environmental stresses such as high temperature and pH conditions. Urease was extracted from bacterial cells to evaluate bacterial urease as an alternative to plantbased ureases. Ureolytic activities and thermal inactivation for both bacterial- and plant-based ureases were similar. Urease became thermally inactivated at elevated temperatures (> 50 °C), and urease activity also decreased when pH values moved away from circumneutral pH conditions, i.e., at pH values < 5 and > 9. Urease stability was improved through immobilization for temperatures up to 60 °C and pH values between 3.7 and 4.7. While suspended urease did not demonstrate any residual activity after a one-hour exposure to pH 4.1 at 60 °C, immobilized urease remained active after the exposure. The studies presented here suggest that UICP technology may be used in a broad range of applications, and urease stability can be improved. The use of bacterially derived urease could be cost-competitive. UICP technology not only has the potential to solve various engineering challenges, but it also has the potential to replace traditional cement technologies and contribute to a more sustainable future.Item Forming parameters and quantification of continous and stretch broken carbon fibers(Montana State University - Bozeman, College of Engineering, 2021) Janicki, Joseph Charles; Chairperson, Graduate Committee: Dilpreet S. Bajwa; This thesis contains two articles of which Joseph Charles Janicki is not the main author.Continuous carbon fibers are premium reinforcing material for aerospace composites. Carbon fiber reinforced polymers are five times stronger than steel and twice as stiff, making it an ideal candidate for structural aircraft components where weight is an important factor. The challenge with continuous carbon fibers is their difficulty to form deep drawn parts requiring intricate manufacturing techniques that increase manufacturing time, cost, and material waste. An alternative to continuous carbon fibers is stretch broken carbon fiber (SBCF). SBCF is a form of aligned discontinuous fiber, it has been proposed as an alternative to overcome this formability challenge. SBCF provides flexibility to form complex shapes while maintaining comparable strength and stiffness. A variety of testing methods have been developed to study both the ability of SBCF to form over traditional continuous carbon fiber and how different iterations of SBCF perform against each other. These include testing carbon fiber tows in tension on a universal test stand as well as designing and creating a forming tool that tests resin impregnated tows under different geometry conditions and temperatures. Tensile properties of both a continuous tow and a SBCF tow were evaluated at different gauge lengths and temperatures. It shows that SBCF tow maximum load increases as the gauge length decreases as well as elevated temperature has a clear effect on the tensile properties when fiber continuity is considered. Cross-sectional areas of continuous and SBCF tows were calculated using both areal weight and scanning electron microscopy showing that in general continuous fiber tows have a larger cross-section than SBCF. Using a forming fixture to test samples, results were statistically analyzed in order to display the significance of geometry and temperature on the maximum forming load of different fibers. The suite of testing and results indicate that in general SBCF maintains superior formability to that of continuous fibers. Overall lower maximum force is required for SBCF to form into deep drawn shapes. This supports their ability to be used more readily in complex aircraft structure while minimizing the disadvantages posed by traditional carbon composites.Item Novel models and observations of energetic events in the solar transition region(Montana State University - Bozeman, College of Letters & Science, 2021) Parker, Jacob Douglas; Chairperson, Graduate Committee: Charles C. Kankelborg; Dana Longcope was a co-author of the article, 'Modeling a propagating sawtooth flare ribbon as a tearing mode in the presence of velocity shear' in the journal 'Astrophysical journal' which is contained within this dissertation.; Charles Kankelborg was a co-author of the article, 'Determining the spectral content of MOSES images' submitted to the journal 'Astrophysical journal' which is contained within this dissertation.; Roy Smart, Charles Kankelborg, Amy Winebarger and Nelson Goldsworth were co-authors of the article, 'First flight of the EUV snapshot imaging spectrograph (ESIS)' submitted to the journal 'Astrophysical journal' which is contained within this dissertation.The solar atmosphere is an energetic and violent place capable of producing eruptions that affect us on earth. In order to better understand these events, so that we might improve out ability to model and predict them, we observe the sun from space to diagnose the local plasma conditions and track its evolution. The transition region, a thin region of the solar atmosphere separating the chromosphere from the corona, is where the solar atmosphere transitions rapidly from ten thousand, to one million kelvin and is therefore thought to play an important roll in the transfer of mass and energy to the hot corona. The sun's magnetic field, and magnetic reconnection, are thought to contribute to the increased temperature of the corona, since the cooler lower solar atmosphere cannot heat it via thermal conduction or convection. Explosive events, small solar eruptions likely driven by magnetic reconnection, are frequent in the transition region, making it an attractive area of the atmosphere to study and gather information on the processes. Using Computed Tomography Imaging Spectrographs (CTIS), capable of measuring spectral line profiles over a wide fields of view at every exposure, we find many eruptive events in the transition region to be spatially complex, three dimensional, and to evolve on rapid timescales. This demonstrates the utility of, and need to continue developing, CTIS style instruments for solar study since they provide a more complete picture of solar events, allowing us to improve our understanding of our closest star.Item Integrating cover crop mixtures in the northern Great Plains: an ecological assessment on crop productivity, biodiversity, and temperature and moisture conditions(Montana State University - Bozeman, College of Agriculture, 2020) DuPre, Mary Ellyn; Chairperson, Graduate Committee: Fabian D. Menalled and Tim F. SeipelCropping systems can impact crop productivity and functioning of biodiversity in the Northern Great Plains, a region heavily reliant on low diversity crop rotations and off-farm inputs, and a region predicted to experience warmer and drier climate scenarios by mid-century. In three complementary studies, I compared the impacts of cover crop mixtures and termination methods on crop productivity and three forms of the associated biodiversity (weeds, soil fungi, and ground beetles), under varying temperature and soil moisture conditions. First, I assessed the impacts of the presence (cover crops and fallow) and composition (cover crop mixtures) of cover crops, termination methods (herbicide, cattle-grazing, and haying), as a function of temperature and soil moisture conditions on crop yields, and weed communities. A 5-species, early-spring mixture generated cooler temperatures, produced more biomass, and suppressed weed biomass under warmer and drier conditions, compared to summer fallow and the 7-species, mid-spring mixture. However, lower soil moisture and subsequent reduced grain yields following the mixtures, especially under warmer and drier conditions, suggests that continuously rotating wheat with mixtures may not be the optimal method to diversify small-grain cropping systems. Second, I assessed the impacts of the presence and composition of cover crops, termination methods and temperature and soil moisture conditions on fungal communities. The early-season cover crop mixture reduced plant pathogen abundance and enhanced AM fungal richness in both the soil and subsequent wheat root crop. The enhancement of beneficial fungi and fewer plant pathogens may be a proxy to better support ecosystem services through the use of cover crop mixtures. Third, I compared ground beetle communities among cover crops treatments and termination methods. Ground beetle activity density was not impacted by termination methods and was greatest in the early-season mixture at the beginning of the growing season and in summer fallow at the end of the growing season, while the mid-season mixture peaked in the middle. Ground beetle diversity peaked in the middle and differed in community composition earlier in the growing season. These results indicate that cover crop mixtures can act as an ecological filter to ground beetle communities to better support pest regulation. Overall, these studies indicate that cover crop mixtures can support crop productivity and the associated biodiversity with changes to temperature and soil moisture, although, with agronomic and ecological trade-offs.Item Exploration of rare-earth ion transitions and host materials for spectral hole burning applications and quantum information science(Montana State University - Bozeman, College of Letters & Science, 2021) Marsh, Aaron Daniel; Chairperson, Graduate Committee: Rufus L. ConeDue to their capacity for generating and manipulating light, the rare-earths are a foundational part of many cutting-edge technologies, ranging from lighting to quantum communications. Optical applications based on rare-earth doped materials are restricted to their transition energies. There are large bands, including the telecom window, where available rare-earth transitions typically have poor properties at liquid helium temperatures. The limitations are determined by the fundamental interactions between rare-earth ions and their host materials; comprehension of the interactions can be leveraged to significantly improve the properties of rare-earth quantum states. Three unexplored rare-earth optical transitions are investigated in this thesis: the Tm 3+ 3 H6<-->3 F3 at ~690 nm, the Pr 3+ 3 H 4<-->3 F 3 at ~1584 nm, and the Tm 3+ 3 F4<-->3 H 4 at ~1451 nm. The first transition suppresses non-radiative relaxation through engineering of the host material phonon spectrum. The 3 F 3 lifetime is extended to ~100 microsecond in Tm 3+ :KPb 2Br 5. The material Tm 3+:LaF 3 is also prepared for high-contrast spectral filtering in ultrasound-optical medical imaging sensitive to blood oxygenation at ~690 nm. Narrow 380 kHz holes are burned; simulations of hole burning indicate that ~60 dB of filtering contrast at ~3MHz is possible. Likewise, non-radiative relaxation is suppressed on the Pr 3+ transition at ~1584 nm in the low-phonon energy host RbPb 2Br 5. Four sites are revealed, with ~2-5 GHz spectrally resolved inhomogeneous broadenings, ~0.5-1 ms T 1 lifetimes, pseudoquadrupole level storage, and ~750 ns coherence times. This material is discussed for use as an L-band quantum memory. The excited state transition of Tm 3+ at ~1451 nm is then explored for quantum memories. High-resolution spectroscopy finds ~1 GHz inhomogeneous broadenings, ~6 ms lifetimes, and laser-limited ~30 MHz holes are burned. Techniques for measuring the properties of excited state transitions are described. Throughout, experimental methods and applications demonstrate the close relationship between lanthanide research and devices. Rare-earth doped crystals are used as an all-optical, high-resolution sensor package for characterizing cryostats in situ, and spectral hole burning characterizes laser performance as a real-time, ~1 MHz resolution spectrum analyzer. The exploration of rare-earth transitions is found to enable new research and new applications, with many other transitions yet to be explored.Item Understanding hydrogeomorphic influences on stream network denitrification and temperature dynamics(Montana State University - Bozeman, College of Agriculture, 2020) Carlson, Samuel Paul; Chairperson, Graduate Committee: Geoffrey PooleThe removal of nitrate from stream networks through the process of denitrification is an important component of local and regional nutrient cycles, but the controls on stream network denitrification rates remain poorly understood. Previous work has demonstrated general effects of stream channel size and nitrate loading rates on network-scale denitrification rates, but has been unable to elucidate connections between the complex environmental template of streams, and resulting denitrification rates. Understanding links between land use and management practices, physical characteristics of streams, and stream denitrification rates is critical to interpreting observed patterns of nitrate in freshwater systems and forming holistic management strategies for reducing the negative effects of elevated nitrate concentrations. To address these critical uncertainties, I developed a stream network simulation model that incorporates the effects of whole-stream aerobic respiration on biotic denitrification demand. This model is applied to a small, subalpine stream network under scenarios designed to explore: 1) the implications of temperature-controlled, network scale patterns of respiration rates on the distribution and overall magnitude of stream network denitrification, and 2) the effect of logging-induced channel simplification on whole network denitrification rates. The first analysis is complimented by an evaluation of controls on stream temperature across this network, revealing the spatially and temporally variable influence of in-network lakes on stream temperatures. Results from the first analysis suggest that reach- and network-scale denitrification rates are strongly influenced by respiration rate and temperature when nitrate supplies are high relative to removal rates, indicating an increased contribution of lower, warmer streams to whole-network denitrification. The second analysis reveals that historical logging has caused a ~30% loss of stream network denitrification capacity, which is manifested as a corresponding reduction in whole-network denitrification rates when nitrate supplies are not limiting. In sum, this work emphasizes the diverse set of factors that influence reach- and watershed-scale biogeochemical characteristics and processes, and suggests that land management actions which influence stream morphology may also alter stream denitrification rates.