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Item Operando optical and quantitative electrochemical studies of solid oxide fuel cell anode degradation and regeneration(Montana State University - Bozeman, College of Letters & Science, 2022) Pomeroy, Elias Deen; Chairperson, Graduate Committee: Robert Walker; This is a manuscript style paper that includes co-authored chapters.Solid Oxide Fuel Cells (SOFCs) are high temperature (600-1000 °C) devices that can generate electricity with extremely high efficiencies from a wide variety of fuels, including H 2, CH 4, Biogas, and crushed coal. Unfortunately, the SOFC anodes are highly sensitive to gas phase contaminants, including sulfur and carbon containing fuels. Sulfur is ubiquitous in all carbon containing fuels, with concentrations as low as a few parts per million to as high as 1% by mass. At all concentrations sulfur substantially decreases SOFC performance. Conventional models propose that sulfur decreases fuel cell performance by blocking anode active sites, preventing electrochemical reactions, and reducing surface area for heterogeneous catalysis. Carbon containing fuels can rapidly degrade SOFCs due to graphitic carbon formation. Graphite blocks active sites on the anode, causes damage within the anode microstructure, and removes electrocatalytic material via metal dusting. Studies presented in this work used operando optical techniques and quantitative electrochemistry to study degradation and remediation of SOFC anodes. First, since typical electrochemical techniques infer microstructural changes rather than directly measuring surface area, a traditional electrochemical technique, chronocoulometry (CC), was adapted to SOFCs for the first time to measure the electrochemically active area of the anode. This technique showed that active area is temperature dependent, and that sulfur participates in electrochemical reactions, decreasing performance with sluggish oxidation kinetics, rather than simply blocking active sites. Carbon monoxide, on the other hand, decreased the number of active sites, rather than participating in electrochemical reactions, either by blocking active sites or forming carbon. Then, a comparative study was undertaken of different methodologies of carbon remediation, comparing electrochemical oxidation, molecular oxygen, and steam as methods to remove graphite accumulated on SOFC anodes. This study found that with all methods, CO 2 played a key role in removing carbon, that both electrochemical oxidation and steam removed carbon more globally than oxygen, and that imaging the entire cell is critical for understanding the complex, spatially and temporally heterogeneous chemistry occurring across SOFC anodes. Finally, sulfur was employed to passivate SOFC anodes operating on dry methane, significantly reducing carbon formation with only slight decreases in electrochemical performance.Item Operando optical studies of next generation anode materials in high temperature solid oxide fuel cells(Montana State University - Bozeman, College of Letters & Science, 2020) Welander, Martha Maria; Chairperson, Graduate Committee: Robert Walker; Marley S. Zachariasen, Clay D. Hunt, Stephen W. Sofie and Robert A. Walker were co-authors of the article, 'Operando studies of redox resiliance in alt enhanced NIO-YSZ SOFC anodes' in the journal 'Journal of the electrochemical society' which is contained within this dissertation.; Marley S. Zachariasen, Stephen W. Sofie and Robert A. Walker were co-authors of the article, 'Enhancing Ni-YSZ anode resilience to environmental redox stress with aluminum titanate secondary phases' in the journal 'ACS applied energy materials' which is contained within this dissertation.; Marley S. Zachariasen, Stephen W. Sofie and Robert A. Walker were co-authors of the article, 'Mitigating carbon formation with Al 2TiO 5 enhanced solid oxide fuel cell anodes' in the journal 'The journal of physical chemistry C' which is contained within this dissertation.; Daniel B. Drasbaek, Marie L. Traulsem Bhaskar R. Sudireddy, Peter Holtappels and Robert A. Walker were co-authors of the article, 'What does carbon tolerant really mean? Operando vibrational studies of carbon accumulation on novel solid ocide fuel cell anodes prepared by infiltration' submitted to the journal 'RSC physical chemistry chemical physics' which is contained within this dissertation.; Disseration contains an article of which Martha Maria Welander is not the main author.Solid oxide fuel cells (SOFCs) are high temperature energy conversion devices capable of efficient and sustainable energy production. Because of the need to electrochemically reduce molecular oxygen and the relatively high activation energy required for oxide ions to diffuse through the dense, solid-state electrolyte, SOFCs typically operate at temperatures > or = 500 °C. High operating temperatures endow SOFCs with many advantages, including fuel flexibility and high conversion efficiencies, distinguishing them from other types of fuel cells. However, high temperatures also present challenges related to the stability of the electrode materials, accelerating cell degradation and limiting the development and integration of SOFCs into large scale power production strategies. These mechanisms are the result of fundamental changes in material properties that remain poorly described and difficult to predict. Studies presented in this work utilized operando Raman spectroscopy and electrochemical measurements to directly correlate material changes with changes in cell performance under various operating conditions. Research focused on developing and characterizing new electro-catalytic materials having improved conversion efficiencies and mechanical resilience to thermal and chemical stress. Because current state of the art SOFC Ni-YSZ cermet anodes are sensitive to oxidation, the first two studies investigated the effects of adding small amounts of Al 2TiO 5 to Ni-YSZ anodes and the impact of resulting secondary (2°) phases that formed on SOFC tolerance to electrochemical and environmental reduction and oxidation (redox) cycling. Results show that Al 2TiO 5 helps improve tolerance to both types of redox cycling by maintaining electrode-electrolyte connectivity and minimizing catalyst coarsening. The third study illustrates how this same dopant improved anode carbon tolerance when operating with hydrocarbon fuels. Because excessive carbon accumulation on SOFC anodes can lead to rapid cell failure, ways to improve carbon tolerance was further explored in the last two studies. These studies investigate the effect of decoupling the electro-catalytic and the electronically conductive phases of the anode under pure methane and biogas-surrogate environments. Collectively, the studies described in this dissertation provide insight into the materials-specific mechanisms responsible for limiting degradation of doped and functionally decoupled anodes to help guide the design of new SOFC electrode materials.Item Characterization of CpI and CpII [FeFe]-hydrogenases reveals properties contributing to catalytic bias(Montana State University - Bozeman, College of Letters & Science, 2016) Artz, Jacob Hansen; Chairperson, Graduate Committee: John W. Peters; Dissertation contains two articles of which Jacob Hansen Artz is not the main author.; David W. Mulder, Michael W. Ratzloff, Saroj Poudel, Axl X. LeVan, S. Garrett Williams, Michael W. W. Adams, Anne K. Jones, Eric S. Boyd, Paul W. King and John W. Peters were co-authors of the article, 'Potentiometric EPR spectral deconvolution of CPI [FeFe]-hydrogenase reveals accessory cluster properties' submitted to the journal 'Journal of the American Chemical Society' which is contained within this thesis.; David W. Mulder, Michael W. Ratzloff, Saroj Poudel, Axl X. LeVan, Michael W. W. Adams, Eric S. Boyd, Paul W. King, and John W. Peters were co-authors of the article, 'EPR and FTIR spectroscopy provides insights into the mechanism of [FeFe]-hydrogenase CPII' submitted to the journal 'Journal of the American Chemical Society' which is contained within this thesis.The need for food, fuel, and pharmaceuticals has been increasing at a growing rate as the world's population increases and lifestyles improve. All of these needs are highly energy dependent, and, to a significant degree, rely on an inefficient use of fossil fuels. In order to break free of this dependence, new understanding is required for how to efficiently generate the products humanity needs. Here, a model system of two closely related [FeFe]-hydrogenases, CpI and CpII, is employed in order to understand how biology is able to efficiently control the formation of reduced products, in order to further delineate the limits of control, and the extent to which biology may be co-opted for technological needs. CpI, one of nature's best catalysts for reducing protons to hydrogen gas, is compared to CpII, which functions catalytically to oxidize hydrogen to protons and electrons. Oxygen sensitivity, midpoint potentials, catalytic mechanisms, and catalytic bias are explored in-depth using electron paramagnetic resonance, Fourier Transform Infrared spectroscopy, and protein film voltammetry. CpI and CpII have been found to function under different metabolic conditions, and key amino acids influencing their distinct behavior have been identified. The conduit arrays of hydrogenases, which direct electrons to or from the active site, have been found to have distinct midpoint potentials in CpII compared to CpI, effectively reversing the favored electron flow through CpII in comparison to CpI. In order to probe the contributions of the protein framework on catalysis, analysis of site-specific amino acid substituted variants have been used to identify several determinants that affect the H-cluster environment, which contributes to the observed differences between CpI and CpII. This has resulted in a deeper understanding of the hydrogenase model system and the ability to directly influence catalytic bias. Thus, the work presented here represents key progress towards developing unidirectional catalysts, and demonstrates the possibility of targeted, rational design and implementation of unidirectional catalysts.Item Mechanistic implications from 'in operando' optical and electrochemical studies of bio-related fuel chemistry in solid oxide fuel cells(Montana State University - Bozeman, College of Letters & Science, 2015) Kirtley, John David; Chairperson, Graduate Committee: Robert Walker; Bryan C. Eigenbrodt and Robert A. Walker were co-authors of the article, 'In situ optical studies of oxidation kinetics of NI/YSZ cermet anodes' in the journal 'ECS transactions' which is contained within this thesis.; David M. Halat, Melissa M. McIntyre, Bryan C. Eigenbrodt and Robert A. Walker were co-authors of the article, 'High temperature 'spectrochronopotentiometry': correlating electrochemical performance with in situ raman spectroscopy in solid oxide fuel cells' in the journal 'Analytical chemistry' which is contained within this thesis.; Melissa M. McIntyre, David M. Halat and Robert A. Walker were co-authors of the article, 'Insights into SOFC NI/YSZ anode degradation using in situ spectrochronopotentiometry' submitted to the journal 'ECS transactions' which is contained within this thesis.; Anand Singh, David Halat, Thomas Oswell, Josephine M. Hill and Robert A. Walker were co-authors of the article, 'In situ raman studies of carbon removal from high temperature NI-YSZ cermet anodes by gas phase reforming agents' submitted to the journal 'Journal of physical chemistry C' which is contained within this thesis.; Daniel A. Steinhurst, Jeffrey C. Owrutsky, Michael B. Pomfret and Robert A. Walker were co-authors of the article, 'In situ optical studies of methane and simulated biogas oxidation on high temperature solid oxide fuel cells' in the journal 'Physical chemistry chemical physics' which is contained within this thesis.; Daniel A. Steinhurst, Jeffrey C. Owrutsky, Michael B. Pomfret and Robert A. Walker were co-authors of the article, 'Towards a working mechanism of fuel oxidation in SOFCS: in situ optical studies of simulated biogas and methane' submitted to the journal 'Journal of physical chemistry C' which is contained within this thesis.Solid oxide fuel cells using bio-renewable fuels promise efficient, sustainable, and clean electricity production, and are becoming more attractive sources of electrical power as global consumption of non-renewables accelerates. The excellent efficiencies of solid oxide fuel cells as solid state electrochemical devices arise mainly from the direct conversion of chemical to electrical energy--through oxygen reduction at the cathode, oxide diffusion through the electrolyte, and fuel oxidation at the anode. Some of these processes possess high activation energies, requiring high operational temperatures (generally > 650 °C). These conditions can hasten deleterious carbon accumulation and anode deterioration. These high operating temperatures also pose significant challenges in directly observing chemical reactions responsible for electrochemical oxidation and materials degradation. Yet, these observations are needed to understand fundamental mechanisms responsible for these processes--an understanding necessary to improve the performance, durability and versatility of SOFCs, especially as these devices are required to operate with complex fuels and fuel mixtures. In this work, solid oxide fuel cells constructed with traditional Ni/yttrium stabilized zirconia ceramic-metallic (or cermet) anodes are studied in operando and in situ with several novel optical techniques (Raman vibrational spectroscopy, near infrared thermal imaging and fourier-transform infrared emission spectroscopy) and electrochemical measurements that provide vital insights into mechanisms surrounding bio-related fuel electrochemistry. The first study demonstrated that Ni oxidation is slower than reduction at the anode. The second study quantified electrochemically accessible anode carbon accumulation under methane fuel, while detailing deleterious mechanisms and microstructural changes that accompany cell polarization in the absence of gas phase fuels. The third study explored the kinetics of carbon removal from Ni-based anodes by CO 2, H 2O, and O 2 and detailed mechanistically why they may be different. The fourth study revealed mechanisms associated with carbon formation and current generation from biogas and methane as a function of operational condition. Collectively, these studies have begun to provide the direct, molecularly specific information necessary to empirically evaluate mechanistic descriptions of biorelated fuel electrochemistry and anode degradation.Item Investigation of the structure of interfaces and transport mechanisms for adsorbed alkylsulfates(Montana State University - Bozeman, College of Letters & Science, 1991) O'Connor, Penny MaureenItem Nonaqueous organometallic electrochemistry : heterogeneous coupling of alkyl halides with reduced iron(Montana State University - Bozeman, College of Letters & Science, 1977) Hall, Jeffrey LouisItem The electrochemical reduction of basic liquid ammonia solutions(Montana State University - Bozeman, College of Engineering, 1970) Wang, Shoou-I