Browsing by Author "Rehbein, Steven M"
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Item Solvent coordination to palladium can invert the selectivity of oxidative addition(Royal Society of Chemistry, 2022-01) Elias, Emily K; Rehbein, Steven M; Neufeldt, Sharon R.In the presence of the bulky monophosphine PtBu3, palladium usually prefers to react with Ar–Cl over Ar–OTf bonds. However, strongly coordinating solvents can bind to palladium, inducing a reversal of selectivity.