Solvent coordination to palladium can invert the selectivity of oxidative addition
Date
2022-01
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
In the presence of the bulky monophosphine PtBu3, palladium usually prefers to react with Ar–Cl over Ar–OTf bonds. However, strongly coordinating solvents can bind to palladium, inducing a reversal of selectivity.
Description
Keywords
solvent coordination, palladium, oxidative addition
Citation
Elias, E. K., Rehbein, S. M., & Neufeldt, S. R. (2022). Solvent coordination to palladium can invert the selectivity of oxidative addition. Chemical science, 13(6), 1618-1628.
Collections
Endorsement
Review
Supplemented By
Referenced By
Creative Commons license
Except where otherwised noted, this item's license is described as cc-by