Theses and Dissertations at Montana State University (MSU)
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Item Tracing interactions of hydrogeology and land use in two Montana watersheds(Montana State University - Bozeman, College of Agriculture, 2024) Keeshin, Skye Ilan; Chairperson, Graduate Committee: Stephanie A. EwingHydrogeologic systems dictate the introduction, transport, processing, and mixing of groundwaters, with implications for both groundwater and surface water quality. Land use can transform hydrogeologic processes and water quality through contributions of human amendments, alteration of soil and aquifer materials, and redistribution and consumption of water resources. Groundwater transit times are also orders of magnitude longer than those of surface water systems, resulting in lag times in water quality changes. In this thesis, I examine water quality consequences of land use in Montana at two headwater sites using geochemical tracers in groundwater and surface water. The first is within the Powder River Basin, the largest coal producing region in the US, where manmade aquifers composed of spoils from mine overburden replace existing unconsolidated and bedrock aquifers with salinity effects on downgradient waters. In a reclaimed coulee supplying groundwater to Rosebud Creek, a tributary of the Yellowstone River, geochemical and isotopic tracers reveal lateral contributions that contribute to dilution of high salinity mine-derived waters. These contributions include local inputs from shallow unconsolidated and bedrock aquifers and inputs of water on the order of 10,000 years from regional bedrock systems. The second site is the Gallatin Valley, a rapidly urbanizing intermountain basin in the Upper Missouri headwaters, where groundwater and surface water transects reveal mixing of water with a range of ages from a few years to 100,000 years. While not associated with spatial variation in nitrate concentration, these contributions likely attenuate rising nitrate concentrations in the valley aquifer as a whole over time, reflecting spatially variable loading from a legacy of agricultural fertilization and increasingly prevalent septic wastewater systems. A large component of the Gallatin Valley aquifer is decades old water sourced from higher elevation precipitation, consistent with long travelled mountain front stream losses. This component may diminish over time with an increasingly limited snowpack. Overall, hydrogeologic systems in these two land use regimes limit but do not eliminate effects of human-derived water quality concerns, and documenting them will improve water quality forecasting with impending changes in snowpack and precipitation.Item The effect of permafrost thaw and geologic substrate on dissolved organic carbon mobilization and transformation in northern streams(Montana State University - Bozeman, College of Agriculture, 2019) Wologo, Ethan Andrew; Chairperson, Graduate Committee: Stephanie A. Ewing; Sarah Shakil, Scott Zolkos, Sadie Textor, Stephanie Ewing, Jane Klassen, Robert G.M. Spencer, David C. Podgorski, Suzanne E. Tank, Michelle A. Baker, Jonathan A. O'Donnell, Kimberly P. Wickland, Sydney S.W. Foks, Jay P. Zarnetske, Joseph Lee-Cullin, Futing Liu, Yuanhe Yang, Pirkko Kortelainen, Jaana Kolehmainen, Joshua F. Dean, Jorien E. Vonk, Robert M. Holmes, Gilles Pinay, Michaela M. Powell, Jansen Howe, Rebecca Frei and Benjamin W. Abbott were co-authors of the article, 'No evience of dissolved organic matter priming in permafrost stream networks: a circumpolar assessment' submitted to the journal 'Global biogeochemical cycles' which is contained within this thesis.; Stephanie Ewing, Jonathan A. O'Donnell, Jim Paces, Rob Striegl, Duane Froese and Joshua Koch were co-authors of the article, 'Groundwater connection and doc transport in the Yukon River Basin: uranium and strontium isotopes in permafrost catchments' submitted to the journal 'Global biogeochemical cycles' which is contained within this thesis.Permafrost landscapes exhibit unique hydrology that is linked both chemically and physically to nutrient cycling and geochemical processes. Permafrost thaw is expected to result in a positive feedback to Earth's climate system through carbon release to the atmosphere; this potential demands better understanding of hydrologic pathways in permafrost landscapes in the face of global change. The work that follows is divided into two main bodies of research that explore both carbon dynamics and isotope geochemistry of river waters draining permafrost catchments in the Yukon River Basin (YRB). The first study uses in-vitro incubations of stream water from seven permafrost regions to investigate how biolabile carbon additions (acetate) and inorganic nutrients (nitrogen and phosphorus) 'prime' water-column dissolved organic carbon (DOC) decomposition. No priming effect from biolabile carbon addition was evident through changes in DOC concentrations or compositional transformations, but consumption of added acetate was correlated with ambient nutrient concentrations. Sites with fine-textured, ice-rich substrate and proximal thermokarst features had higher ambient DOC and nutrient concentrations, and consequently the fastest rates of acetate consumption. We conclude that the fate of biolabile DOC released from degrading permafrost will depend largely on inorganic nutrient availability in receiving waterbodies. The second part of this thesis focuses on hydrology of intermediate-sized catchments in the YRB. We evaluate uranium isotope activity ratios ([234U/238U]) as tracers of groundwater-surface water connection in thawing permafrost landscapes. Streams draining loess-mantled areas had [234U/238U] values moderately increased relative to meteoric values. Streams draining low-order catchments with rocky substrate and surface disturbance exhibit dramatically increased [234U/238U] values, consistent with groundwater connection. In addition, we observed higher DOC concentrations both in areas influenced by recent thaw and where flow is restricted by ice-rich silt. The transformation of northern stream chemistry will likely continue as northern permafrost environents warm, with greatest resilience of ground ice in loess-blanketed areas not subject to thermal erosion by groundwater. As subsurface storage expands and groundwater exchange intensifies, ecosystems within and connected to northern streams will also be transformed, with implications for resource managers concerned with fish and wildlife management in these systems.Item SR and U isotopes reveal interactions of surface water and groundwater along the mountain headwaters to intermountain basin transition (Hyalite Canyon and Gallatin Valley, MT)(Montana State University - Bozeman, College of Agriculture, 2018) Miller, Florence Rita; Chairperson, Graduate Committee: Stephanie A. Ewing; Stephanie A. Ewing, Robert A. Payn, James B. Paces, Sam Leuthold and Stephan Custer were co-authors of the article, 'SR and U isotopes reveal the influence of lithologic structure on stream-groundwater interaction along a mountain headwater catchment (Hyalite Canyon, MT)' submitted to the journal 'Water resources research' which is contained within this thesis.; Stephanie A. Ewing, Robert Payn, Sam Leuthold, Stephan Custer, Tom Michalek and James B. Paces were co-authors of the article, 'SR and U isotopes reveal mixing patterns of groundwater and surface water influenced by human management in an intermountain basin (Gallatin Valley, MT)' submitted to the journal 'Journal of hydrology' which is contained within this thesis.Mountainous regions of the western United States are characterized by steep, rapidly eroding mountain headwater streams transitioning to more depositional intermountain basins. The character and flux of water across these process domains is subject to projected changes in mountain headwater snowpack and agricultural and urban land use in rapidly developing intermountain basins. Here we evaluate controls on water/rock, water/substrate, and surface/groundwater interactions within Hyalite Creek and the Gallatin Valley of southwest Montana. We use solute loads and geochemical tracers (87 Sr/86 Sr, Ca/Sr, and [234U/238U]) as indicators of such interactions. Surface water, groundwater, and soil samples were collected between 2016 and 2018. Stream water in upper Hyalite Creek had low 87 Sr/86 Sr values typical of volcanic and sedimentary host rock units, and low [234 U/238 U] values consistent with shorter flow path soil, shallow aquifer or runoff water. Middle Hyalite Creek had increased [234 U/238 U] values, reflecting groundwater inflows from the Madison Group limestones. Lower Hyalite Creek had an increase in 87 Sr/86 Sr values and decrease in [234 U/238 U] values, indicated contributions from Archean gneiss fracture flow. Using mixing models, we estimate inflows from the Madison contribute ~4% during summer baseflow conditions and inflows from the Archean contribute ~2% to ~8% of streamflow during summer and winter baseflow conditions. At the mountain front, diverse Ca/Sr, 87Sr/86Sr, and [234U/238U] ratios were observed as a result of convergent flow in mountain headwaters catchments. In the intermountain basin, divergent flow at the mountain front recharges valley aquifers and combines with infiltration through soils. With distance down-valley, we observe intermediate values of Ca/Sr, 87 Sr/86 Sr, and [234 U/238 U], suggesting mixing of diverse source waters. Higher concentrations of Sr, alkalinity, and Ca/Sr and 87 Sr/86 Sr ratios consistent with soil carbonates suggest water infiltration through soil facilitated the influence of soil secondary carbonates on groundwater geochemistry. Additionally, increased water movement through soil facilitates the increase in anthropogenic loading of NO3- and Cl- in surface and groundwaters. Our results provide novel quantification of groundwater contribution to streamflow in mountain headwaters, and elucidate water quality and quantity controls from the mountain front across the intermountain basin, including valley aquifer recharge, infiltration through soils, and anthropogenic solute influxes to groundwater.Item Groundwater nitrate transport and residence time in a vulnerable aquifer under dryland cereal production(Montana State University - Bozeman, College of Agriculture, 2013) Miller, Christine Ross; Chairperson, Graduate Committee: Stephanie A. Ewing; Stephanie A. Ewing, W. Adam Sigler, E. N. J. Brookshire, Clain A. Jones, Douglas Jackson-Smith and Gary S. Weissmann were co-authors of the article, 'Groundwater nitrate transport and residence time in a vulnerable aquifer under dryland cereal production' submitted to the journal 'Journal of geophysical research - biogeosciences' which is contained within this thesis.Selection of agricultural management practices to reduce nitrate leaching from soils can only be successful if both nitrate loading rates from soils to shallow aquifers and groundwater residence times are quantified. Elevated nitrate concentrations in shallow unconfined aquifers are commonly observed in agricultural areas as a result of increased N inputs. In the Judith River Watershed (JRW) in central Montana, USA, notably high nitrate concentrations in groundwater and stream water have exceeded the U.S. EPA drinking water standard of 10 mg L -1 for at least two decades. This large (24,400 ha) watershed drains immediately into the Missouri River, a tributary of the Mississippi River. Over an eleven month period in 2012, we measured groundwater and surface water nitrate concentrations across a hydrologically isolated strath terrace. We use the resulting data to constrain nitrate accumulation dynamics in the shallow aquifer. Nitrate is relatively conservative in this location, as it is high in groundwater (17.57 +/- 4.29 mg L -1; all groundwater samples pooled together), and remains high in streams and springs that drain the landform (15.67 +/- 9.45 mg L -1; all surface water and spring samples pooled together). We use a numerical model to simulate the character of nitrate accumulation in the aquifer as a whole, in order to evaluate how the entire period of cultivation has contributed to current nitrate concentrations, and begin to predict response times for effects of land use change. We consider the effect of groundwater residence time and travel time on nitrate loading using particle tracking in a three dimensional model aquifer. We find no correlation with nitrate concentrations in groundwater and emerging surface waters, and suggest approaches for improving both the geometry of the model and the selection of sites in future work. Overall, our results imply that groundwater residence times are several decades at most, suggesting that similar timeframes will be needed to reduce overall nitrate concentrations in groundwater and emergent streams to below drinking water standards. Preliminary evaluation of several management scenarios suggests that both increased fertilizer use efficiency and rotational strategies may be needed to prevent the loss of soil N to groundwater.Item Soil and terrain attributes for evaluation of leaching in a Montana farm field(Montana State University - Bozeman, College of Agriculture, 1995) Landon, Melissa AnnItem Mineralization of nitrogen and carbon in adjacent crop-fallow and native range soils(Montana State University - Bozeman, College of Agriculture, 1995) Neill, Karnes EdwinItem Remediation of acid rock drainage through the use of a constructed passive treatment system which simulates natural processes(Montana State University - Bozeman, College of Agriculture, 1997) Schmidt, T.G.Item Soil water and solute movement in Montana strip mine spoils(Montana State University - Bozeman, College of Agriculture, 1976) Arnold, Franklin BrooksItem A premining soil water drainage study on a natural soil(Montana State University - Bozeman, College of Agriculture, 1982) Noel, Roy DuaneItem The effect of irrigation on soil and groundwater quality in the Huntley Irrigation District, Montana(Montana State University - Bozeman, College of Agriculture, 1980) Moncrief, John Frazeur