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Item Anisotropy in Anomalies of Hypersound Velocity and Attenuation in Ferroelectric TSCC(1985-01) Hikita, T.; Wang, J. T.; Schnackenberg, P. T.; Schmidt, V. HugoFrom Brillouin shift and linewidth of longitudinal phonons propagating along the [100] and [001] directions of TSCC, the polarization relaxation time was calculated to be τ=3.1×10-12/(Tc-T) sec below the transition temperature Tc. The anomalies in the longitudinal phonons of the [010] propagation were carefully examined using an annealed crystal of excellent quality. No essential difference was observed between the velocities of a normal and high quality crystals. The relaxation time was deduced as a function of temperature from the observed anomalies in the velocity and linewidth. Spectra are observed for nearly forward scattering from the q\varparallel[010] phonons.Item Brillouin scattering near the ferroelectric phase transition in TSCC(1985-06) Hikita, T.; Schnackenberg, P. T.; Schmidt, V. HugoBrillouin spectra from longitudinal phonons in ferroelectric tris-sarcosine calcium chloride (TSCC) propagating along [100], [010] and [001] have been measured as functions of temperature. Large anomalies were found in the Brillouin shift and linewidth in the [100] and [001] phonons. These anomalies are interpreted as arising from the linear coupling of the polarization and phonons. From the the temperature where the linewidth is maximum, the relaxation time of the polarization fluctuations is estimated to be τ = 3.1×10−12/(Tc−T) sec, where Tc is the ferroelectric transition temperature. We also observed anomalies in Brillouin shift and linewidth of the [010] phonons which propagate along the ferroelectric axis. These anomalies are interpreted as coming from electrostrictive coupling. The energy relaxation time was estimated to be τE=2.5×10−10/(T−Tc) sec in the paraelectric (PE) phase and τE=1.0x10−9/(T−Tc) sec in the ferroelectric (FE) phase, by comparing our Brillouin results with those f the ultrasonic measurements.Item Brillouin scattering study of the ferroelectric phase transition in tris-sarcosine calcium chloride(1985-01) Hikita, T.; Schnackenberg, P. T.; Schmidt, V. HugoBrillouin spectra from longitudinal phonons in ferroelectric tris-sarcosine calcium chloride propagating along [100], [010], and [001] have been measured as functions of temperature. Large anomalies were found in the Brillouin shift and linewidth in the [100] and [001] phonons. These anomalies are interpreted as arising from the linear coupling of the polarization and the phonons. From the temperature where the linewidth is maximum, the relaxation time of the polarization fluctuations is estimated to be τ=3.1×10−12/(Tc-T) sec, where Tc is the ferroelectric transition temperature. We also observed anomalies in Brillouin shift and linewidth of the [010] phonons which propagate along the ferroelectric b axis. These anomalies are interpreted as coming from electro- strictive coupling. The energy-relaxation time was estimated to be τE=2.5×10−10/(T-Tc) sec in the paraelectric phase and τE=1.0×10−9/(Tc-T) sec in the ferroelectric phase, by comparing our Brillouin results with those of the ultrasonic measurements.