Chemistry & Biochemistry

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The Department of Chemistry and Biochemistry offers research-oriented programs culminating in the Doctor of Philosophy degree. The faculty in the department have expertise over a broad range of specialty areas including synthesis, structure, spectroscopy, and mechanism. In each of these fields, the strength of the department has been recognized at the international level.

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Author: search.filters.author.Elias, Emily K

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    Solvent coordination to palladium can invert the selectivity of oxidative addition
    (Royal Society of Chemistry, 2022-01) Elias, Emily K; Rehbein, Steven M; Neufeldt, Sharon R.
    In the presence of the bulky monophosphine PtBu3, palladium usually prefers to react with Ar–Cl over Ar–OTf bonds. However, strongly coordinating solvents can bind to palladium, inducing a reversal of selectivity.
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